Synthesis of trifluoromethylamino-substituted pyridines and pyrimidines by oxidative desulfurization-fluorination

Manabu Kuroboshi; Katsuya Mizuno; Kiyoshi Kanie; Tamejiro Hiyama

doi:10.1016/0040-4039(94)02253-8

Synthesis of trifluoromethylamino-substituted pyridines and pyrimidines by oxidative desulfurization-fluorination

Manabu Kuroboshi, Katsuya Mizuno, Kiyoshi Kanie, Tamejiro Hiyama

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

Oxidative desulfurization-fluorination of methyl N-pyridyl(or N-pyrimidyl)-N-alkyldithiocarbamates gave the corresponding trifluoromethylamino-substituted pyridines (or pyrimidines), which underwent cross-coupling reaction to give a new type of liquid crystalline compounds having trifluoromethylamino group.

Original language	English
Pages (from-to)	563-566
Number of pages	4
Journal	Tetrahedron Letters
Volume	36
Issue number	4
DOIs	https://doi.org/10.1016/0040-4039(94)02253-8
Publication status	Published - 1995 Jan 23
Externally published	Yes

Keywords

Dithiocarbamate
Oxidative desulfurization-fluorination
Trifluoromethylamine

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/0040-4039(94)02253-8

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title = "Synthesis of trifluoromethylamino-substituted pyridines and pyrimidines by oxidative desulfurization-fluorination",

abstract = "Oxidative desulfurization-fluorination of methyl N-pyridyl(or N-pyrimidyl)-N-alkyldithiocarbamates gave the corresponding trifluoromethylamino-substituted pyridines (or pyrimidines), which underwent cross-coupling reaction to give a new type of liquid crystalline compounds having trifluoromethylamino group.",

keywords = "Dithiocarbamate, Oxidative desulfurization-fluorination, Trifluoromethylamine",

author = "Manabu Kuroboshi and Katsuya Mizuno and Kiyoshi Kanie and Tamejiro Hiyama",

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doi = "10.1016/0040-4039(94)02253-8",

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T1 - Synthesis of trifluoromethylamino-substituted pyridines and pyrimidines by oxidative desulfurization-fluorination

AU - Kuroboshi, Manabu

AU - Mizuno, Katsuya

AU - Kanie, Kiyoshi

AU - Hiyama, Tamejiro

N1 - Funding Information: AcknowledgmentT: he presenrte searchw as partiallys upportebdy a Grant-in-AidN o. 05750764fo r Encouragemeonft Y oungS cientistfsr omt heM inistryo f EducationS,c iencea ndC ulturea nda lsob y a Grant-in-Aid from AsahiG lassF oundatio(nJ apan)f or theP romotiono f Science.

PY - 1995/1/23

Y1 - 1995/1/23

N2 - Oxidative desulfurization-fluorination of methyl N-pyridyl(or N-pyrimidyl)-N-alkyldithiocarbamates gave the corresponding trifluoromethylamino-substituted pyridines (or pyrimidines), which underwent cross-coupling reaction to give a new type of liquid crystalline compounds having trifluoromethylamino group.

AB - Oxidative desulfurization-fluorination of methyl N-pyridyl(or N-pyrimidyl)-N-alkyldithiocarbamates gave the corresponding trifluoromethylamino-substituted pyridines (or pyrimidines), which underwent cross-coupling reaction to give a new type of liquid crystalline compounds having trifluoromethylamino group.

KW - Dithiocarbamate

KW - Oxidative desulfurization-fluorination

KW - Trifluoromethylamine

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

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ER -

Synthesis of trifluoromethylamino-substituted pyridines and pyrimidines by oxidative desulfurization-fluorination

Abstract

Keywords

ASJC Scopus subject areas

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