Synthesis, structure, and properties of a stable 1,2-dibromodialumane(4) bearing a bulky aryl substituent

Tomohiro Agou; Koichi Nagata; Heisuke Sakai; Yukio Furukawa; Norihiro Tokitoh

doi:10.1021/om300237q

Synthesis, structure, and properties of a stable 1,2-dibromodialumane(4) bearing a bulky aryl substituent

Tomohiro Agou, Koichi Nagata, Heisuke Sakai, Yukio Furukawa, Norihiro Tokitoh

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

The stable 1,2-dibromodialumane(4) Bbp(Br)Al-Al(Br)Bbp (1; Bbp = 2,6-bis[bis(trimethylsilyl)methyl]phenyl) was synthesized by the reduction of the corresponding dibromoalumane etherate BbpAlBr ₂•OEt ₂ (2). The structure and properties of 1 have been elucidated on the basis of the analyses of spectroscopic and crystallographic data and are supported by DFT calculations.

Original language	English
Pages (from-to)	3806-3809
Number of pages	4
Journal	Organometallics
Volume	31
Issue number	9
DOIs	https://doi.org/10.1021/om300237q
Publication status	Published - 2012 May 14
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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title = "Synthesis, structure, and properties of a stable 1,2-dibromodialumane(4) bearing a bulky aryl substituent",

abstract = "The stable 1,2-dibromodialumane(4) Bbp(Br)Al-Al(Br)Bbp (1; Bbp = 2,6-bis[bis(trimethylsilyl)methyl]phenyl) was synthesized by the reduction of the corresponding dibromoalumane etherate BbpAlBr 2•OEt 2 (2). The structure and properties of 1 have been elucidated on the basis of the analyses of spectroscopic and crystallographic data and are supported by DFT calculations.",

author = "Tomohiro Agou and Koichi Nagata and Heisuke Sakai and Yukio Furukawa and Norihiro Tokitoh",

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T1 - Synthesis, structure, and properties of a stable 1,2-dibromodialumane(4) bearing a bulky aryl substituent

AU - Agou, Tomohiro

AU - Nagata, Koichi

AU - Sakai, Heisuke

AU - Furukawa, Yukio

AU - Tokitoh, Norihiro

PY - 2012/5/14

Y1 - 2012/5/14

N2 - The stable 1,2-dibromodialumane(4) Bbp(Br)Al-Al(Br)Bbp (1; Bbp = 2,6-bis[bis(trimethylsilyl)methyl]phenyl) was synthesized by the reduction of the corresponding dibromoalumane etherate BbpAlBr 2•OEt 2 (2). The structure and properties of 1 have been elucidated on the basis of the analyses of spectroscopic and crystallographic data and are supported by DFT calculations.

AB - The stable 1,2-dibromodialumane(4) Bbp(Br)Al-Al(Br)Bbp (1; Bbp = 2,6-bis[bis(trimethylsilyl)methyl]phenyl) was synthesized by the reduction of the corresponding dibromoalumane etherate BbpAlBr 2•OEt 2 (2). The structure and properties of 1 have been elucidated on the basis of the analyses of spectroscopic and crystallographic data and are supported by DFT calculations.

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Synthesis, structure, and properties of a stable 1,2-dibromodialumane(4) bearing a bulky aryl substituent

Abstract

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