Synthesis, structure, and redox properties of diphosphathienoquinones

Fumiki Murakami; Shigeru Sasaki; Masaaki Yoshifuji

doi:10.1002/1521-3773(20020715)41:14<2574::AID-ANIE2574>3.0.CO;2-K

Synthesis, structure, and redox properties of diphosphathienoquinones

Fumiki Murakami, Shigeru Sasaki, Masaaki Yoshifuji

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

The first diphosphaheteroquinoid compound, which contains two low-coordinate phosphorus atoms and a thienoquinoid skeleton (see picture), was isolated as air-stable orange crystals. Its quinoid nature was confirmed by x-ray crystallography and cyclic voltammetry, which revealed the expected redox behavior.

Original language	English
Pages (from-to)	2574-2576
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	41
Issue number	14
DOIs	https://doi.org/10.1002/1521-3773(20020715)41:14<2574::AID-ANIE2574>3.0.CO;2-K
Publication status	Published - 2002 Jul 15

Keywords

Phosphaalkenes
Quinones
Radical ions
Redox chemistry
Sulfur heterocycles

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Access to Document

10.1002/1521-3773(20020715)41:14<2574::AID-ANIE2574>3.0.CO;2-K

Cite this

@article{cf4c8f3ebb8743e9963f245ca187ddd8,

title = "Synthesis, structure, and redox properties of diphosphathienoquinones",

abstract = "The first diphosphaheteroquinoid compound, which contains two low-coordinate phosphorus atoms and a thienoquinoid skeleton (see picture), was isolated as air-stable orange crystals. Its quinoid nature was confirmed by x-ray crystallography and cyclic voltammetry, which revealed the expected redox behavior.",

keywords = "Phosphaalkenes, Quinones, Radical ions, Redox chemistry, Sulfur heterocycles",

author = "Fumiki Murakami and Shigeru Sasaki and Masaaki Yoshifuji",

year = "2002",

month = jul,

day = "15",

doi = "10.1002/1521-3773(20020715)41:14<2574::AID-ANIE2574>3.0.CO;2-K",

language = "English",

volume = "41",

pages = "2574--2576",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "14",

}

TY - JOUR

T1 - Synthesis, structure, and redox properties of diphosphathienoquinones

AU - Murakami, Fumiki

AU - Sasaki, Shigeru

AU - Yoshifuji, Masaaki

PY - 2002/7/15

Y1 - 2002/7/15

N2 - The first diphosphaheteroquinoid compound, which contains two low-coordinate phosphorus atoms and a thienoquinoid skeleton (see picture), was isolated as air-stable orange crystals. Its quinoid nature was confirmed by x-ray crystallography and cyclic voltammetry, which revealed the expected redox behavior.

AB - The first diphosphaheteroquinoid compound, which contains two low-coordinate phosphorus atoms and a thienoquinoid skeleton (see picture), was isolated as air-stable orange crystals. Its quinoid nature was confirmed by x-ray crystallography and cyclic voltammetry, which revealed the expected redox behavior.

KW - Phosphaalkenes

KW - Quinones

KW - Radical ions

KW - Redox chemistry

KW - Sulfur heterocycles

UR - http://www.scopus.com/inward/record.url?scp=0037099456&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0037099456&partnerID=8YFLogxK

U2 - 10.1002/1521-3773(20020715)41:14<2574::AID-ANIE2574>3.0.CO;2-K

DO - 10.1002/1521-3773(20020715)41:14<2574::AID-ANIE2574>3.0.CO;2-K

M3 - Article

C2 - 12203538

AN - SCOPUS:0037099456

SN - 1433-7851

VL - 41

SP - 2574

EP - 2576

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 14

ER -

Synthesis, structure, and redox properties of diphosphathienoquinones

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this