@article{4454d0b9fd454c8295f8de6d65246695,
title = "Synthetic Studies on Amphirionin-5: Stereochemical Assignment/Reassignment of the C1-C9 Portion through Stereodivergent Synthesis",
abstract = "Synthesis of four diastereomers of the C1-C12 fragment of amphirionin-5 has been achieved in a convergent and stereodivergent manner. Detailed comparison of the 1H and 13C NMR data of each compound with those reported for the natural product led to not only the stereochemical assignment of the relative configuration of the C4/C5 stereogenic centers but also reassignment of the proposed relative configuration at C9 of amphirionin-5.",
author = "Moemi Kanto and Makoto Sasaki",
note = "Funding Information: We thank Professor Masashi Tsuda (Kochi University) for providing us with the NMR spectra of amphirionin-5 and Professor Haruhiko Fuwa (Tohoku University) for helpful discussions. This work was financially supported in part by a Grant-in-Aid from Scientific Research (B) (No. 25282228) and Scientific Research on Innovative Areas {"}Chemical Biology of Natural Products{"} (No. 23102016)27 from the Japan Society for the Promotion of Science (JSPS). Publisher Copyright: {\textcopyright} 2015 American Chemical Society.",
year = "2016",
month = jan,
day = "4",
doi = "10.1021/acs.orglett.5b03346",
language = "English",
volume = "18",
pages = "112--115",
journal = "Organic Letters",
issn = "1523-7060",
publisher = "American Chemical Society",
number = "1",
}