@article{a4467121510645ccb908b5e96245c2b1,
title = "Synthetic Studies on Presporolide, a Putative Enediyne Precursor of Sporolides",
abstract = "A synthesis of the core framework of presporolide, which possesses both a strained bicyclo[7.3.0]dodecadiyne moiety and a distinctive macrolactone structure, is reported. This synthesis features: (i) a Cu-mediated O-arylation of a hindered tertiary alcohol using triarylbismuth reagent; (ii) stereoselective construction of the strained nine-membered diyne ring; and (iii) atroposelective formation of the macrolactone.",
author = "Shuji Yamashita and Kanae Terayama and Eri Ozeki and Yujiro Hayashi and Masahiro Hirama",
note = "Funding Information: This work was supported financially by JSPS KAKENHI Grant No. 24590003, a Grant-in-Aid for Specially Promoted Research from the Ministry of Education, Culture, Sports, Science and Technology (MEXT), a SUNBOR GRANT from the Suntory Institute for Bioorganic Research, and by a grant from the NOVARTIS Foundation (Japan) for the Promotion of Science (No. 12-106). Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",
year = "2018",
month = jan,
day = "5",
doi = "10.1021/acs.orglett.7b03670",
language = "English",
volume = "20",
pages = "276--279",
journal = "Organic Letters",
issn = "1523-7060",
publisher = "American Chemical Society",
number = "1",
}