TY - JOUR
T1 - Tetra-potassium hepta-cyanido-molybdate(III) dihydrate
AU - Nakabayashi, Koji
AU - Tomono, Keisuke
AU - Tsunobuchi, Yoshihide
AU - Kosaka, Wataru
AU - Ohkoshi, Shin Ichi
PY - 2009
Y1 - 2009
N2 - The asymmetric unit of the title compound, KI 4[Mo III(CN)7]·2H2O, consists of one [Mo(CN)7] 4- anion, four K+ cations, and two water mol-ecules. The [MoIII(CN)7]4- anion has a seven-coordinated capped-trigonal-prismatic coordination geometry. The site-occupancy factors of the disordered water mol-ecules were set at 0.90, 0.60 and 0.50. The H-atom positions could not be determined for two of the water mol-ecules. The H atoms of the water with a site-occupancy factor of 0.90 were refined using O- H and H⋯H distance restraints.
AB - The asymmetric unit of the title compound, KI 4[Mo III(CN)7]·2H2O, consists of one [Mo(CN)7] 4- anion, four K+ cations, and two water mol-ecules. The [MoIII(CN)7]4- anion has a seven-coordinated capped-trigonal-prismatic coordination geometry. The site-occupancy factors of the disordered water mol-ecules were set at 0.90, 0.60 and 0.50. The H-atom positions could not be determined for two of the water mol-ecules. The H atoms of the water with a site-occupancy factor of 0.90 were refined using O- H and H⋯H distance restraints.
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U2 - 10.1107/S1600536809039336
DO - 10.1107/S1600536809039336
M3 - Article
AN - SCOPUS:70449394174
SN - 1600-5368
VL - 65
SP - i79-i80
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 11
ER -