TY - JOUR
T1 - The abundance of potassium in the Earth's core
AU - Watanabe, Kosui
AU - Ohtani, Eiji
AU - Kamada, Seiji
AU - Sakamaki, Tatsuya
AU - Miyahara, Masaaki
AU - Ito, Yoshinori
N1 - Funding Information:
We thank Y. Asahara for useful discussions, and N. Nishitani, S. Takahashi, and T. Sakairi for experimental assistance. This work was supported by a Grant-in-Aid for Scientific Research from the Ministry of Education, Culture, Science, Sport and Technology of the Japanese Government (Nos. 1804009 and 22000002 ) to E.O. This work was also supported partly by the Ministry of Education and Science of Russian Federation , project 14.B25.31.0032 to E.O. This study was conducted as part of a Global COE Program, “Global Education and Research Center for Earth and Planetary Dynamics,” at Tohoku University.
Publisher Copyright:
© 2014 Elsevier B.V.
PY - 2014/12/1
Y1 - 2014/12/1
N2 - We studied partitioning of potassium (K) between aluminosilicate (adularia, KAlSi3O8) and metals with and without light elements, oxygen and silicon (Fe-O, Fe-Si, and pure Fe metals). We conducted experiments at pressures up to 50GPa, temperatures up to 3500K, and oxygen fugacities (log fO2) between 2.5 and 4.0 log units below the iron-wüstite (IW) buffer using a double-sided laser-heated diamond anvil cell. Our results on pressure, temperature, and compositional effects on partition coefficient of potassium, DK (i.e., the content of potassium in metal [wt%] divided by the content of potassium in silicate [wt%]), revealed that the temperature effect is slightly positive but weaker than that reported previously, whereas the pressure effect is negative. Oxygen in metal increases the potassium content in metal, whereas silicon in metal has the opposite effect. According to the present study on potassium partitioning, we estimated that the amount of potassium in the core is less than 40ppm and that it generates less than 0.17TW heat in the core. The amount of heat generated in the core is very small compared with the heat escaping from the core at the core-mantle boundary (5-15TW).
AB - We studied partitioning of potassium (K) between aluminosilicate (adularia, KAlSi3O8) and metals with and without light elements, oxygen and silicon (Fe-O, Fe-Si, and pure Fe metals). We conducted experiments at pressures up to 50GPa, temperatures up to 3500K, and oxygen fugacities (log fO2) between 2.5 and 4.0 log units below the iron-wüstite (IW) buffer using a double-sided laser-heated diamond anvil cell. Our results on pressure, temperature, and compositional effects on partition coefficient of potassium, DK (i.e., the content of potassium in metal [wt%] divided by the content of potassium in silicate [wt%]), revealed that the temperature effect is slightly positive but weaker than that reported previously, whereas the pressure effect is negative. Oxygen in metal increases the potassium content in metal, whereas silicon in metal has the opposite effect. According to the present study on potassium partitioning, we estimated that the amount of potassium in the core is less than 40ppm and that it generates less than 0.17TW heat in the core. The amount of heat generated in the core is very small compared with the heat escaping from the core at the core-mantle boundary (5-15TW).
KW - Earth's core
KW - High pressure
KW - High temperature
KW - Magma ocean
KW - Partition coefficient
KW - Potassium
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U2 - 10.1016/j.pepi.2014.10.001
DO - 10.1016/j.pepi.2014.10.001
M3 - Article
AN - SCOPUS:84909581430
SN - 0031-9201
VL - 237
SP - 65
EP - 72
JO - Physics of the Earth and Planetary Interiors
JF - Physics of the Earth and Planetary Interiors
ER -