The corrosion behavior of amorphous and crystalline Ni-10Ta-20P alloys in 12M HCl

H. J. Lee; E. Akiyama; H. Habazaki; A. Kawashima; K. Asami; K. Hashimoto

doi:10.1016/0010-938X(96)00016-9

The corrosion behavior of amorphous and crystalline Ni-10Ta-20P alloys in 12M HCl

H. J. Lee, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

Materials Design Division

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

The addition of a large amount of phosphorus, such as 20 at%, to arc-melted crystalline and rapidly quenched amorphous Ni-10Ta alloys greatly enhances the corrosion resistance in 12 M HCl at 30°C. The corrosion rate of the rapidly quenched amorphous Ni-10Ta-20P alloy after immersion for 168 h is about one order of magnitude lower than that of the arc-melted crystalline counterpart. The open circuit potentials of both alloys are initially ennobled by accumulation of elemental phosphorus having a high activity for the cathodic oxygen reduction. The open circuit potential is further ennobled by spontaneous passivation. The ennoblement of the open circuit potential of the amorphous alloy is faster than that of the crystalline counterpart, because of faster passivation as a result of the formation of a tantalum-enriched passive film.

Original language	English
Pages (from-to)	1269-1279
Number of pages	11
Journal	Corrosion Science
Volume	38
Issue number	8
DOIs	https://doi.org/10.1016/0010-938X(96)00016-9
Publication status	Published - 1996 Aug

Keywords

A. alloy
B. EPMA
B. SEM
B. XPS
C. passive films

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)
Materials Science(all)

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10.1016/0010-938X(96)00016-9

Cite this

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abstract = "The addition of a large amount of phosphorus, such as 20 at%, to arc-melted crystalline and rapidly quenched amorphous Ni-10Ta alloys greatly enhances the corrosion resistance in 12 M HCl at 30°C. The corrosion rate of the rapidly quenched amorphous Ni-10Ta-20P alloy after immersion for 168 h is about one order of magnitude lower than that of the arc-melted crystalline counterpart. The open circuit potentials of both alloys are initially ennobled by accumulation of elemental phosphorus having a high activity for the cathodic oxygen reduction. The open circuit potential is further ennobled by spontaneous passivation. The ennoblement of the open circuit potential of the amorphous alloy is faster than that of the crystalline counterpart, because of faster passivation as a result of the formation of a tantalum-enriched passive film.",

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AU - Lee, H. J.

AU - Akiyama, E.

AU - Habazaki, H.

AU - Kawashima, A.

AU - Asami, K.

AU - Hashimoto, K.

PY - 1996/8

Y1 - 1996/8

N2 - The addition of a large amount of phosphorus, such as 20 at%, to arc-melted crystalline and rapidly quenched amorphous Ni-10Ta alloys greatly enhances the corrosion resistance in 12 M HCl at 30°C. The corrosion rate of the rapidly quenched amorphous Ni-10Ta-20P alloy after immersion for 168 h is about one order of magnitude lower than that of the arc-melted crystalline counterpart. The open circuit potentials of both alloys are initially ennobled by accumulation of elemental phosphorus having a high activity for the cathodic oxygen reduction. The open circuit potential is further ennobled by spontaneous passivation. The ennoblement of the open circuit potential of the amorphous alloy is faster than that of the crystalline counterpart, because of faster passivation as a result of the formation of a tantalum-enriched passive film.

AB - The addition of a large amount of phosphorus, such as 20 at%, to arc-melted crystalline and rapidly quenched amorphous Ni-10Ta alloys greatly enhances the corrosion resistance in 12 M HCl at 30°C. The corrosion rate of the rapidly quenched amorphous Ni-10Ta-20P alloy after immersion for 168 h is about one order of magnitude lower than that of the arc-melted crystalline counterpart. The open circuit potentials of both alloys are initially ennobled by accumulation of elemental phosphorus having a high activity for the cathodic oxygen reduction. The open circuit potential is further ennobled by spontaneous passivation. The ennoblement of the open circuit potential of the amorphous alloy is faster than that of the crystalline counterpart, because of faster passivation as a result of the formation of a tantalum-enriched passive film.

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KW - B. SEM

KW - B. XPS

KW - C. passive films

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The corrosion behavior of amorphous and crystalline Ni-10Ta-20P alloys in 12M HCl

Abstract

Keywords

ASJC Scopus subject areas

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