The crystal structure of Sr6Cu3N5 with isolated, bent (CuI2N3)7- anions and the single crystal structural determination of SrCuN

F. J. DiSalvo; S. S. Trail; H. Yamane; N. E. Brese

doi:10.1016/S0925-8388(96)02811-3

The crystal structure of Sr₆Cu₃N₅ with isolated, bent (Cu^I₂N₃)^7- anions and the single crystal structural determination of SrCuN

F. J. DiSalvo, S. S. Trail, H. Yamane, N. E. Brese

IMRAM - Division of Inorganic Material Research

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

Single crystals of the ternary nitrides Sr₆Cu₃N₅ and SrCuN were prepared in high pressure autoclaves at 800 °C. Tetragonal crystals of the nitridocuprate, Sr₆Cu₃N₅ crystallized in space group P4₂mc (no. 105), a=8.649(1) Å, c=7.325(1) Å. This compound represents a new structure type characterized by a mixture of linear (Cu^IN₂)^5- and unprecedented V-shaped (Cu^I₂N₃)^7- nitridometallate anions. The crystal structure of SrCuN was confirmed by single crystal data to adopt the BaNiN structure type (Pnma (no. 62), a=9.045(2), b=13.234(3), c=5.388(1) Å; Z=12).

Original language	English
Pages (from-to)	122-129
Number of pages	8
Journal	Journal of Alloys and Compounds
Volume	255
Issue number	1-2
DOIs	https://doi.org/10.1016/S0925-8388(96)02811-3
Publication status	Published - 1997 Jun 22

Keywords

Azide
Crystal
Flux
Nitride
Nitridometallate
Structure

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10.1016/S0925-8388(96)02811-3

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title = "The crystal structure of Sr6Cu3N5 with isolated, bent (CuI2N3)7- anions and the single crystal structural determination of SrCuN",

abstract = "Single crystals of the ternary nitrides Sr6Cu3N5 and SrCuN were prepared in high pressure autoclaves at 800 °C. Tetragonal crystals of the nitridocuprate, Sr6Cu3N5 crystallized in space group P42mc (no. 105), a=8.649(1) {\AA}, c=7.325(1) {\AA}. This compound represents a new structure type characterized by a mixture of linear (CuIN2)5- and unprecedented V-shaped (CuI2N3)7- nitridometallate anions. The crystal structure of SrCuN was confirmed by single crystal data to adopt the BaNiN structure type (Pnma (no. 62), a=9.045(2), b=13.234(3), c=5.388(1) {\AA}; Z=12).",

keywords = "Azide, Crystal, Flux, Nitride, Nitridometallate, Structure",

author = "DiSalvo, {F. J.} and Trail, {S. S.} and H. Yamane and Brese, {N. E.}",

note = "Funding Information: We are grateful for support of this work by the NSF through grant #DMR-9508522. This work made use of the MSC electron microscope facility, an MRL central facility supported by the National Science Foundation under award number DMR-912564. We would like to thank Cien Kowach for useful discussions and Emil Lobkovsky I'or aid with the structure detern!ination",

year = "1997",

month = jun,

day = "22",

doi = "10.1016/S0925-8388(96)02811-3",

language = "English",

volume = "255",

pages = "122--129",

journal = "Journal of Alloys and Compounds",

issn = "0925-8388",

publisher = "Elsevier BV",

number = "1-2",

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TY - JOUR

T1 - The crystal structure of Sr6Cu3N5 with isolated, bent (CuI2N3)7- anions and the single crystal structural determination of SrCuN

AU - DiSalvo, F. J.

AU - Trail, S. S.

AU - Yamane, H.

AU - Brese, N. E.

N1 - Funding Information: We are grateful for support of this work by the NSF through grant #DMR-9508522. This work made use of the MSC electron microscope facility, an MRL central facility supported by the National Science Foundation under award number DMR-912564. We would like to thank Cien Kowach for useful discussions and Emil Lobkovsky I'or aid with the structure detern!ination

PY - 1997/6/22

Y1 - 1997/6/22

N2 - Single crystals of the ternary nitrides Sr6Cu3N5 and SrCuN were prepared in high pressure autoclaves at 800 °C. Tetragonal crystals of the nitridocuprate, Sr6Cu3N5 crystallized in space group P42mc (no. 105), a=8.649(1) Å, c=7.325(1) Å. This compound represents a new structure type characterized by a mixture of linear (CuIN2)5- and unprecedented V-shaped (CuI2N3)7- nitridometallate anions. The crystal structure of SrCuN was confirmed by single crystal data to adopt the BaNiN structure type (Pnma (no. 62), a=9.045(2), b=13.234(3), c=5.388(1) Å; Z=12).

AB - Single crystals of the ternary nitrides Sr6Cu3N5 and SrCuN were prepared in high pressure autoclaves at 800 °C. Tetragonal crystals of the nitridocuprate, Sr6Cu3N5 crystallized in space group P42mc (no. 105), a=8.649(1) Å, c=7.325(1) Å. This compound represents a new structure type characterized by a mixture of linear (CuIN2)5- and unprecedented V-shaped (CuI2N3)7- nitridometallate anions. The crystal structure of SrCuN was confirmed by single crystal data to adopt the BaNiN structure type (Pnma (no. 62), a=9.045(2), b=13.234(3), c=5.388(1) Å; Z=12).

KW - Azide

KW - Crystal

KW - Flux

KW - Nitride

KW - Nitridometallate

KW - Structure

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U2 - 10.1016/S0925-8388(96)02811-3

DO - 10.1016/S0925-8388(96)02811-3

M3 - Article

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SN - 0925-8388

VL - 255

SP - 122

EP - 129

JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

IS - 1-2

ER -

The crystal structure of Sr₆Cu₃N₅ with isolated, bent (Cu^I₂N₃)^7- anions and the single crystal structural determination of SrCuN

Abstract

Keywords

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