The determination of the third body efficiencies for the H+O 2+M=HO2+M reaction (M=Ar, H2O)

Youhi Morii; Nobuyuki Tsuboi; Mitsuo Koshi; Hiroyuki Ogawa; A. Koichi Hayashi; Taro Shimizu

The determination of the third body efficiencies for the H+O ₂+M=HO₂+M reaction (M=Ar, H₂O)

Youhi Morii, Nobuyuki Tsuboi, Mitsuo Koshi, Hiroyuki Ogawa, A. Koichi Hayashi, Taro Shimizu

IFS - Global Collaborative Research and Education Center for Integrated Flow Science (IFS-GCORE)

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The detailed chemical reaction model for H₂/O₂ combustion proposed by Koshi was estimated in a high pressure state. In this paper, two rate coefficients of the terminating reactions are discussed. The numerical ignition delay time in H₂/O₂/ Ar mixture were compared with the experiments measured by Petersen et al. and the rate coefficient of the reaction H+ O₂+Ar→HO₂+Ar was decided as k=2.96×10¹⁹T^-140. The numerical laminar flame velocity in H₂/O₂/H₂O mixture at various pressures is compared with the experimental data measured by Kusharin et al. The rate coefficient of the reaction H +O₂+H²O→HO ₂+H₂O is determined as k=1.62×10²³T ^-229.

Original language	English
Pages (from-to)	117-121
Number of pages	5
Journal	Science and Technology of Energetic Materials
Volume	70
Issue number	5-6
Publication status	Published - 2009 Sept

Keywords

Detailed chemical reaction model
H/o combustion
High pressure

Cite this

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title = "The determination of the third body efficiencies for the H+O 2+M=HO2+M reaction (M=Ar, H2O)",

abstract = "The detailed chemical reaction model for H2/O2 combustion proposed by Koshi was estimated in a high pressure state. In this paper, two rate coefficients of the terminating reactions are discussed. The numerical ignition delay time in H2/O2/ Ar mixture were compared with the experiments measured by Petersen et al. and the rate coefficient of the reaction H+ O2+Ar→HO2+Ar was decided as k=2.96×1019T-140. The numerical laminar flame velocity in H2/O2/H2O mixture at various pressures is compared with the experimental data measured by Kusharin et al. The rate coefficient of the reaction H +O2+H2O→HO 2+H2O is determined as k=1.62×1023T -229.",

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author = "Youhi Morii and Nobuyuki Tsuboi and Mitsuo Koshi and Hiroyuki Ogawa and {Koichi Hayashi}, A. and Taro Shimizu",

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T1 - The determination of the third body efficiencies for the H+O 2+M=HO2+M reaction (M=Ar, H2O)

AU - Morii, Youhi

AU - Tsuboi, Nobuyuki

AU - Koshi, Mitsuo

AU - Ogawa, Hiroyuki

AU - Koichi Hayashi, A.

AU - Shimizu, Taro

PY - 2009/9

Y1 - 2009/9

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AB - The detailed chemical reaction model for H2/O2 combustion proposed by Koshi was estimated in a high pressure state. In this paper, two rate coefficients of the terminating reactions are discussed. The numerical ignition delay time in H2/O2/ Ar mixture were compared with the experiments measured by Petersen et al. and the rate coefficient of the reaction H+ O2+Ar→HO2+Ar was decided as k=2.96×1019T-140. The numerical laminar flame velocity in H2/O2/H2O mixture at various pressures is compared with the experimental data measured by Kusharin et al. The rate coefficient of the reaction H +O2+H2O→HO 2+H2O is determined as k=1.62×1023T -229.

KW - Detailed chemical reaction model

KW - H/o combustion

KW - High pressure

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The determination of the third body efficiencies for the H+O ₂+M=HO₂+M reaction (M=Ar, H₂O)

Abstract

Keywords

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