The first isolation of 1,3-diaza-2-sila-4-cyclopentene radical cation salt: The x-ray structure and electronic properties

Shintaro Ishida; Tohru Nishinaga; Koichi Komatsu

doi:10.1246/cl.2005.486

The first isolation of 1,3-diaza-2-sila-4-cyclopentene radical cation salt: The x-ray structure and electronic properties

Shintaro Ishida, Tohru Nishinaga, Koichi Komatsu

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The first TPFPB salt of 1,3-diaza-2-sila-4-cyclopentene (DASCP) radical cation was isolated as an orange crystalline solid by one-electron oxidation of the neutral DASCP with Ag(I) ion. The X-ray structural analysis and theoretical studies showed that the silicon atom plays an important role in stabilization of this cationic species.

Original language	English
Pages (from-to)	486-487
Number of pages	2
Journal	Chemistry Letters
Volume	34
Issue number	4
DOIs	https://doi.org/10.1246/cl.2005.486
Publication status	Published - 2005 Apr 5
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.2005.486

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The first isolation of 1,3-diaza-2-sila-4-cyclopentene radical cation salt: The x-ray structure and electronic properties

Abstract

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