The first proton-conducting metallic ion-radical salts

Akane Akutsu-Sato; Hiroki Akutsu; Scott S. Turner; Peter Day; Michael R. Probert; Judith A.K. Howard; Tomoyuki Akutagawa; Sadamu Takeda; Takayoshi Nakamura; Takehiko Mori

doi:10.1002/anie.200461686

The first proton-conducting metallic ion-radical salts

Akane Akutsu-Sato, Hiroki Akutsu, Scott S. Turner, Peter Day, Michael R. Probert, Judith A.K. Howard, Tomoyuki Akutagawa, Sadamu Takeda, Takayoshi Nakamura, Takehiko Mori

IMRAM - Materials-Measurement Hybrid Research Center

Research output: Contribution to journal › Article › peer-review

47 Citations (Scopus)

Abstract

Any old ion? Two bis(ethylenedithio)-tetrathiafulvalene (BEDT-TTF) radical salts with ion channels of stacked [18]crown-6 and Cat/H₂O molecules (Cat = H₃O⁺ or NH₄⁺) are described. The structures contain alternating BEDT-TTF layers, [(Cat)M(C₂O ₄)₃]^2- (M = Ga, Cr) layers, and the [18]crown-6 ion channels (see picture). The salts are metallic electrical conductors, and they show high protonic conductivity.

Original language	English
Pages (from-to)	292-295
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	44
Issue number	2
DOIs	https://doi.org/10.1002/anie.200461686
Publication status	Published - 2004 Dec 27

Keywords

Conducting materials
Electron transport
Ion channels
Proton transport

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10.1002/anie.200461686

Cite this

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abstract = "Any old ion? Two bis(ethylenedithio)-tetrathiafulvalene (BEDT-TTF) radical salts with ion channels of stacked [18]crown-6 and Cat/H2O molecules (Cat = H3O+ or NH4+) are described. The structures contain alternating BEDT-TTF layers, [(Cat)M(C2O 4)3]2- (M = Ga, Cr) layers, and the [18]crown-6 ion channels (see picture). The salts are metallic electrical conductors, and they show high protonic conductivity.",

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T1 - The first proton-conducting metallic ion-radical salts

AU - Akutsu-Sato, Akane

AU - Akutsu, Hiroki

AU - Turner, Scott S.

AU - Day, Peter

AU - Probert, Michael R.

AU - Howard, Judith A.K.

AU - Akutagawa, Tomoyuki

AU - Takeda, Sadamu

AU - Nakamura, Takayoshi

AU - Mori, Takehiko

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Y1 - 2004/12/27

N2 - Any old ion? Two bis(ethylenedithio)-tetrathiafulvalene (BEDT-TTF) radical salts with ion channels of stacked [18]crown-6 and Cat/H2O molecules (Cat = H3O+ or NH4+) are described. The structures contain alternating BEDT-TTF layers, [(Cat)M(C2O 4)3]2- (M = Ga, Cr) layers, and the [18]crown-6 ion channels (see picture). The salts are metallic electrical conductors, and they show high protonic conductivity.

AB - Any old ion? Two bis(ethylenedithio)-tetrathiafulvalene (BEDT-TTF) radical salts with ion channels of stacked [18]crown-6 and Cat/H2O molecules (Cat = H3O+ or NH4+) are described. The structures contain alternating BEDT-TTF layers, [(Cat)M(C2O 4)3]2- (M = Ga, Cr) layers, and the [18]crown-6 ion channels (see picture). The salts are metallic electrical conductors, and they show high protonic conductivity.

KW - Conducting materials

KW - Electron transport

KW - Ion channels

KW - Proton transport

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The first proton-conducting metallic ion-radical salts

Abstract

Keywords

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