The L23-VV auger spectra for the Px3 molecules: X = H, F, Cl

F. P. Larkinst; E. Z. Chelkowskat; Y. Sato; Kiyoshi Ueda; E. Shigemasa; A. Yagishita

doi:10.1088/0953-4075/26/8/014

The L₂₃-VV auger spectra for the Px₃ molecules: X = H, F, Cl

F. P. Larkinst, E. Z. Chelkowskat, Y. Sato, Kiyoshi Ueda, E. Shigemasa, A. Yagishita

Division of Measurements

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

The L₂₃-VV Auger spectra for phosphorous atoms in the PH₃, PF₃ and PCI= molecules have been recorded following 2p core-hole ionization induced by photons with energy in the range 150-170 eV. The chlorine L₂₃-VV spectrum for the PCI₃ molecule has also been recorded. The spectra have been interpreted with the aid of molecular Auger calculations. Differences due to chemical effects are identified and a valuable insight is gained into the major pathways available for Auger decay resulting in complex spectral profiles. Predictions are made for the phosphorous 2p inherent photoelectron linewidth in these molecules.

Original language	English
Pages (from-to)	1479-1490
Number of pages	12
Journal	Journal of Physics B: Atomic, Molecular and Optical Physics
Volume	26
Issue number	8
DOIs	https://doi.org/10.1088/0953-4075/26/8/014
Publication status	Published - 1993 Apr 28

ASJC Scopus subject areas

Atomic and Molecular Physics, and Optics
Condensed Matter Physics

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abstract = "The L23-VV Auger spectra for phosphorous atoms in the PH3, PF3 and PCI= molecules have been recorded following 2p core-hole ionization induced by photons with energy in the range 150-170 eV. The chlorine L23-VV spectrum for the PCI3 molecule has also been recorded. The spectra have been interpreted with the aid of molecular Auger calculations. Differences due to chemical effects are identified and a valuable insight is gained into the major pathways available for Auger decay resulting in complex spectral profiles. Predictions are made for the phosphorous 2p inherent photoelectron linewidth in these molecules.",

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T1 - The L23-VV auger spectra for the Px3 molecules

T2 - X = H, F, Cl

AU - Larkinst, F. P.

AU - Chelkowskat, E. Z.

AU - Sato, Y.

AU - Ueda, Kiyoshi

AU - Shigemasa, E.

AU - Yagishita, A.

PY - 1993/4/28

Y1 - 1993/4/28

N2 - The L23-VV Auger spectra for phosphorous atoms in the PH3, PF3 and PCI= molecules have been recorded following 2p core-hole ionization induced by photons with energy in the range 150-170 eV. The chlorine L23-VV spectrum for the PCI3 molecule has also been recorded. The spectra have been interpreted with the aid of molecular Auger calculations. Differences due to chemical effects are identified and a valuable insight is gained into the major pathways available for Auger decay resulting in complex spectral profiles. Predictions are made for the phosphorous 2p inherent photoelectron linewidth in these molecules.

AB - The L23-VV Auger spectra for phosphorous atoms in the PH3, PF3 and PCI= molecules have been recorded following 2p core-hole ionization induced by photons with energy in the range 150-170 eV. The chlorine L23-VV spectrum for the PCI3 molecule has also been recorded. The spectra have been interpreted with the aid of molecular Auger calculations. Differences due to chemical effects are identified and a valuable insight is gained into the major pathways available for Auger decay resulting in complex spectral profiles. Predictions are made for the phosphorous 2p inherent photoelectron linewidth in these molecules.

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The L₂₃-VV auger spectra for the Px₃ molecules: X = H, F, Cl

Abstract

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