The synergistic effect of nanoporous aupd alloy catalysts on highly chemoselective 1,4-hydrosilylation of conjugated cyclic enones

Qiang Chen; Shinya Tanaka; Takeshi Fujita; Luyang Chen; Taketoshi Minato; Yoshifumi Ishikawa; Mingwei Chen; Naoki Asao; Yoshinori Yamamoto; Tienan Jin

doi:10.1039/c3cc49524h

The synergistic effect of nanoporous aupd alloy catalysts on highly chemoselective 1,4-hydrosilylation of conjugated cyclic enones

Qiang Chen, Shinya Tanaka, Takeshi Fujita, Luyang Chen, Taketoshi Minato, Yoshifumi Ishikawa, Mingwei Chen, Naoki Asao, Yoshinori Yamamoto, Tienan Jin

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

The nanoporous AuPd (AuPdNPore) alloy catalyst showed superior chemoselectivity and high catalytic activity for the direct 1,4-hydrosilylation of the conjugated cyclic enones with hydrosilane in comparison with the monometallic nanoporous Au and Pd catalysts. The enhanced catalytic properties of AuPdNPore arise mainly from the nanoporous structure and the synergistic effect of the AuPd alloy.

Original language	English
Pages (from-to)	3344-3346
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	25
DOIs	https://doi.org/10.1039/c3cc49524h
Publication status	Published - 2014 Feb 27

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title = "The synergistic effect of nanoporous aupd alloy catalysts on highly chemoselective 1,4-hydrosilylation of conjugated cyclic enones",

abstract = "The nanoporous AuPd (AuPdNPore) alloy catalyst showed superior chemoselectivity and high catalytic activity for the direct 1,4-hydrosilylation of the conjugated cyclic enones with hydrosilane in comparison with the monometallic nanoporous Au and Pd catalysts. The enhanced catalytic properties of AuPdNPore arise mainly from the nanoporous structure and the synergistic effect of the AuPd alloy.",

author = "Qiang Chen and Shinya Tanaka and Takeshi Fujita and Luyang Chen and Taketoshi Minato and Yoshifumi Ishikawa and Mingwei Chen and Naoki Asao and Yoshinori Yamamoto and Tienan Jin",

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T1 - The synergistic effect of nanoporous aupd alloy catalysts on highly chemoselective 1,4-hydrosilylation of conjugated cyclic enones

AU - Chen, Qiang

AU - Tanaka, Shinya

AU - Fujita, Takeshi

AU - Chen, Luyang

AU - Minato, Taketoshi

AU - Ishikawa, Yoshifumi

AU - Chen, Mingwei

AU - Asao, Naoki

AU - Yamamoto, Yoshinori

AU - Jin, Tienan

PY - 2014/2/27

Y1 - 2014/2/27

N2 - The nanoporous AuPd (AuPdNPore) alloy catalyst showed superior chemoselectivity and high catalytic activity for the direct 1,4-hydrosilylation of the conjugated cyclic enones with hydrosilane in comparison with the monometallic nanoporous Au and Pd catalysts. The enhanced catalytic properties of AuPdNPore arise mainly from the nanoporous structure and the synergistic effect of the AuPd alloy.

AB - The nanoporous AuPd (AuPdNPore) alloy catalyst showed superior chemoselectivity and high catalytic activity for the direct 1,4-hydrosilylation of the conjugated cyclic enones with hydrosilane in comparison with the monometallic nanoporous Au and Pd catalysts. The enhanced catalytic properties of AuPdNPore arise mainly from the nanoporous structure and the synergistic effect of the AuPd alloy.

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U2 - 10.1039/c3cc49524h

DO - 10.1039/c3cc49524h

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VL - 50

SP - 3344

EP - 3346

JO - Chemical Communications

JF - Chemical Communications

IS - 25

ER -

The synergistic effect of nanoporous aupd alloy catalysts on highly chemoselective 1,4-hydrosilylation of conjugated cyclic enones

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