The Two‐Dimensional Network Structure and Metamagnetic Properties of the 2:1 Complex of [Mn(3‐MeOsalen)(H2O)]ClO4 and K3[Fe(CN)6]

Hitoshi Miyasaka; Naohide Matsumoto; Hisashi Ōkawa; Nazzareno Re; Emma Gallo; Carlo Floriani

doi:10.1002/anie.199514461

The Two‐Dimensional Network Structure and Metamagnetic Properties of the 2:1 Complex of [Mn(3‐MeOsalen)(H₂O)]ClO₄ and K₃[Fe(CN)₆]

Hitoshi Miyasaka, Naohide Matsumoto, Hisashi Ōkawa, Nazzareno Re, Emma Gallo, Carlo Floriani

IMR - Materials Development Division

Research output: Contribution to journal › Article › peer-review

144 Citations (Scopus)

Abstract

Cyclic tetrameric units (··Mn‐NC‐Fe‐CN··)₄ (depicted on the right) construct the two‐dimensional network of the title compound. The layers thus formed are linked together by van der Waals contacts. The compound displays metamagnetism: ferromagnetic coupling is observed within layers and antiferromagnetic coupling between layers. (Figure Presented.)

Original language	English
Pages (from-to)	1446-1448
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	34
Issue number	13-14
DOIs	https://doi.org/10.1002/anie.199514461
Publication status	Published - 1995 Jul 31

Keywords

Prussian blue
magnetic properties
manganese compounds
salen complexes

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10.1002/anie.199514461

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AU - Miyasaka, Hitoshi

AU - Matsumoto, Naohide

AU - Ōkawa, Hisashi

AU - Re, Nazzareno

AU - Gallo, Emma

AU - Floriani, Carlo

PY - 1995/7/31

Y1 - 1995/7/31

N2 - Cyclic tetrameric units (··Mn‐NC‐Fe‐CN··)4 (depicted on the right) construct the two‐dimensional network of the title compound. The layers thus formed are linked together by van der Waals contacts. The compound displays metamagnetism: ferromagnetic coupling is observed within layers and antiferromagnetic coupling between layers. (Figure Presented.)

AB - Cyclic tetrameric units (··Mn‐NC‐Fe‐CN··)4 (depicted on the right) construct the two‐dimensional network of the title compound. The layers thus formed are linked together by van der Waals contacts. The compound displays metamagnetism: ferromagnetic coupling is observed within layers and antiferromagnetic coupling between layers. (Figure Presented.)

KW - Prussian blue

KW - magnetic properties

KW - manganese compounds

KW - salen complexes

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The Two‐Dimensional Network Structure and Metamagnetic Properties of the 2:1 Complex of [Mn(3‐MeOsalen)(H₂O)]ClO₄ and K₃[Fe(CN)₆]

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Keywords

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