Theory of quadrupole contributions from interface and bulk in second-order optical processes

Kazuya Shiratori; Akihiro Morita

doi:10.1246/bcsj.20120167

Theory of quadrupole contributions from interface and bulk in second-order optical processes

Kazuya Shiratori, Akihiro Morita

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

32 Citations (Scopus)

Abstract

A unified treatment of the dipole and quadrupole contributions to the second-order optical response is developed. The concept of the effective susceptibility is expanded to incorporate both the surface and bulk contributions. This treatment allows us to quantitatively evaluate both surface and bulk contributions in experimental SFG/SHG spectra. The present theory clarifies a number of qualitative features in the quadrupole contribution, and is thereby utilized to settle recent confusions about the quadrupole and/or bulk effects on the surface nonlinear spectroscopy.

Original language	English
Pages (from-to)	1061-1076
Number of pages	16
Journal	Bulletin of the Chemical Society of Japan
Volume	85
Issue number	10
DOIs	https://doi.org/10.1246/bcsj.20120167
Publication status	Published - 2012

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10.1246/bcsj.20120167

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Theory of quadrupole contributions from interface and bulk in second-order optical processes

Abstract

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