Thermal equilibrium between a lattice-framework disilene and the corresponding silylene

Shinobu Tsutsui; Hiromasa Tanaka; Eunsang Kwon; Shigeki Matsumoto; Kenkichi Sakamoto

doi:10.1021/om049306v

Thermal equilibrium between a lattice-framework disilene and the corresponding silylene

Shinobu Tsutsui, Hiromasa Tanaka, Eunsang Kwon, Shigeki Matsumoto, Kenkichi Sakamoto

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

The existence of the thermal equilibrium between 2,3,4,6,7,8,2′, 3′,4′, &, 7′,8′-dodeca-tert-butyl[5,5′]-bi{1, 5-disilatricyclo[4.2.0.0^1,4]octylidene}-2,7,2′, 7′-tetraene and the corresponding silylene was revealed by trapping experiments. The equilibrium was investigated by DFT calculations.

Original language	English
Pages (from-to)	5659-5661
Number of pages	3
Journal	Organometallics
Volume	23
Issue number	24
DOIs	https://doi.org/10.1021/om049306v
Publication status	Published - 2004 Nov 22
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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abstract = "The existence of the thermal equilibrium between 2,3,4,6,7,8,2′, 3′,4′, &, 7′,8′-dodeca-tert-butyl[5,5′]-bi{1, 5-disilatricyclo[4.2.0.01,4]octylidene}-2,7,2′, 7′-tetraene and the corresponding silylene was revealed by trapping experiments. The equilibrium was investigated by DFT calculations.",

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AU - Tsutsui, Shinobu

AU - Tanaka, Hiromasa

AU - Kwon, Eunsang

AU - Matsumoto, Shigeki

AU - Sakamoto, Kenkichi

PY - 2004/11/22

Y1 - 2004/11/22

N2 - The existence of the thermal equilibrium between 2,3,4,6,7,8,2′, 3′,4′, &, 7′,8′-dodeca-tert-butyl[5,5′]-bi{1, 5-disilatricyclo[4.2.0.01,4]octylidene}-2,7,2′, 7′-tetraene and the corresponding silylene was revealed by trapping experiments. The equilibrium was investigated by DFT calculations.

AB - The existence of the thermal equilibrium between 2,3,4,6,7,8,2′, 3′,4′, &, 7′,8′-dodeca-tert-butyl[5,5′]-bi{1, 5-disilatricyclo[4.2.0.01,4]octylidene}-2,7,2′, 7′-tetraene and the corresponding silylene was revealed by trapping experiments. The equilibrium was investigated by DFT calculations.

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Thermal equilibrium between a lattice-framework disilene and the corresponding silylene

Abstract

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