Thermally induced structural transformation in a hydrogen-bonded supramolecular single-crystal: DSC-FTIR studies

D. Ishii; T. Yamada; M. Nakagawa; T. Iyoda; H. Yoshida

doi:10.1007/s10973-006-7893-7

Thermally induced structural transformation in a hydrogen-bonded supramolecular single-crystal: DSC-FTIR studies

D. Ishii, T. Yamada, M. Nakagawa, T. Iyoda, H. Yoshida

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The thermally induced structural transformation of a hydrogen-bonded crystal formed from an amphoteric molecule of 6-[2-methoxy-4-(pyridylazo) phenoxy]hexanoic acid MeO was studied using differential scanning calorimetry (DSC), Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction measurement (XRD). Crystal form of the hydrogen-bonded crystal was measured by single crystal four circle diffractometer (Mo-K_α radiation). As a result, the crystal of MeO was stabilized by many C-H⋯O hydrogen bonds, and the C-H⋯O hydrogen bonds were broken by thermal energy reversibly. After transformation the supramolecular architecture was composed of supramolecular polymer including free-rotation pentamethylene main chains.

Original language	English
Pages (from-to)	681-685
Number of pages	5
Journal	Journal of Thermal Analysis and Calorimetry
Volume	86
Issue number	3
DOIs	https://doi.org/10.1007/s10973-006-7893-7
Publication status	Published - 2006 Dec
Externally published	Yes

Keywords

Amphoteric compound
C-H⋯O
Crystal structure
DSC-FTIR
Hydrogen bond
Rotator phase
Structural transition
Supramolecular polymer

ASJC Scopus subject areas

Condensed Matter Physics
Physical and Theoretical Chemistry

Access to Document

10.1007/s10973-006-7893-7

Cite this

@article{6ba98ad4663946d3945d486a8d51065a,

title = "Thermally induced structural transformation in a hydrogen-bonded supramolecular single-crystal: DSC-FTIR studies",

abstract = "The thermally induced structural transformation of a hydrogen-bonded crystal formed from an amphoteric molecule of 6-[2-methoxy-4-(pyridylazo) phenoxy]hexanoic acid MeO was studied using differential scanning calorimetry (DSC), Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction measurement (XRD). Crystal form of the hydrogen-bonded crystal was measured by single crystal four circle diffractometer (Mo-Kα radiation). As a result, the crystal of MeO was stabilized by many C-H⋯O hydrogen bonds, and the C-H⋯O hydrogen bonds were broken by thermal energy reversibly. After transformation the supramolecular architecture was composed of supramolecular polymer including free-rotation pentamethylene main chains.",

keywords = "Amphoteric compound, C-H⋯O, Crystal structure, DSC-FTIR, Hydrogen bond, Rotator phase, Structural transition, Supramolecular polymer",

author = "D. Ishii and T. Yamada and M. Nakagawa and T. Iyoda and H. Yoshida",

year = "2006",

month = dec,

doi = "10.1007/s10973-006-7893-7",

language = "English",

volume = "86",

pages = "681--685",

journal = "Journal of Thermal Analysis and Calorimetry",

issn = "1388-6150",

publisher = "Springer Netherlands",

number = "3",

}

TY - JOUR

T1 - Thermally induced structural transformation in a hydrogen-bonded supramolecular single-crystal

T2 - DSC-FTIR studies

AU - Ishii, D.

AU - Yamada, T.

AU - Nakagawa, M.

AU - Iyoda, T.

AU - Yoshida, H.

PY - 2006/12

Y1 - 2006/12

N2 - The thermally induced structural transformation of a hydrogen-bonded crystal formed from an amphoteric molecule of 6-[2-methoxy-4-(pyridylazo) phenoxy]hexanoic acid MeO was studied using differential scanning calorimetry (DSC), Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction measurement (XRD). Crystal form of the hydrogen-bonded crystal was measured by single crystal four circle diffractometer (Mo-Kα radiation). As a result, the crystal of MeO was stabilized by many C-H⋯O hydrogen bonds, and the C-H⋯O hydrogen bonds were broken by thermal energy reversibly. After transformation the supramolecular architecture was composed of supramolecular polymer including free-rotation pentamethylene main chains.

AB - The thermally induced structural transformation of a hydrogen-bonded crystal formed from an amphoteric molecule of 6-[2-methoxy-4-(pyridylazo) phenoxy]hexanoic acid MeO was studied using differential scanning calorimetry (DSC), Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction measurement (XRD). Crystal form of the hydrogen-bonded crystal was measured by single crystal four circle diffractometer (Mo-Kα radiation). As a result, the crystal of MeO was stabilized by many C-H⋯O hydrogen bonds, and the C-H⋯O hydrogen bonds were broken by thermal energy reversibly. After transformation the supramolecular architecture was composed of supramolecular polymer including free-rotation pentamethylene main chains.

KW - Amphoteric compound

KW - C-H⋯O

KW - Crystal structure

KW - DSC-FTIR

KW - Hydrogen bond

KW - Rotator phase

KW - Structural transition

KW - Supramolecular polymer

UR - http://www.scopus.com/inward/record.url?scp=33845461806&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33845461806&partnerID=8YFLogxK

U2 - 10.1007/s10973-006-7893-7

DO - 10.1007/s10973-006-7893-7

M3 - Article

AN - SCOPUS:33845461806

SN - 1388-6150

VL - 86

SP - 681

EP - 685

JO - Journal of Thermal Analysis and Calorimetry

JF - Journal of Thermal Analysis and Calorimetry

IS - 3

ER -

Thermally induced structural transformation in a hydrogen-bonded supramolecular single-crystal: DSC-FTIR studies

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this