Thermoelastic martensite and shape memory effect in ductile Cu-Al-Mn alloys

R. Kainuma, S. Takahashi, K. Ishida

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240 Citations (Scopus)


Ductile shape memory (SM) alloys of the Cu-Al-Mn system have been developed by controlling the degree of order in the β phase. Additions of Mn to the binary Cu-Al alloy stabilize the β phase and widen the single-phase region to lower temperature and lower Al contents. It is shown that Cu-Al-Mn alloys with low Al contents have either the disordered A2 structure or the ordered L21 structure with a lower degree of order and that they exhibit excellent ductility. The disordered A2 phase martensitically transforms to the disordered A1 phase with a high density of twins. The martensite phase formed from the ordered L21 phase has the 18R structure. The SM effect accompanies both the A2 → A1 and L21 → 18R martensitic transformations. These alloys exhibit 15 pct strain to failure, 60 to 90 pct rolling reduction without cracking, and 80 to 90 pct recovery from bend test in the martensitic condition. Experimental results on the microstructure, crystal structure, mechanical properties, and shape memory behavior in the ductile Cu-Al-Mn alloys are presented and discussed.

Original languageEnglish
Pages (from-to)2187-2195
Number of pages9
JournalMetallurgical and Materials Transactions A: Physical Metallurgy and Materials Science
Issue number8
Publication statusPublished - 1996


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