Topological modulation of the porous structure of a coordination polymer constructed from a flexible building block via framework-guest interaction during self-assembly

Atsuko Masuya-Suzuki; Nozomi Matsubara; Ryunosuke Karashimada; Hitoshi Hoshino; Nobuhiko Iki

doi:10.1039/c5ce01804h

Topological modulation of the porous structure of a coordination polymer constructed from a flexible building block via framework-guest interaction during self-assembly

Atsuko Masuya-Suzuki, Nozomi Matsubara, Ryunosuke Karashimada, Hitoshi Hoshino, Nobuhiko Iki

ENV - Frontier Science for Advanced Environment

Tohoku University

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The porous structure of a coordination polymer constructed from a Sm(iii) ion and a conformationally flexible ligand is modulated by guest solvent molecules. The coordination polymer containing the guest DMF molecule possesses isolated hydrophobic and hydrophilic voids, while the one containing the guest methanol molecule has a microchannel with alternately arranged hydrophobic-hydrophilic surfaces.

Original language	English
Pages (from-to)	872-876
Number of pages	5
Journal	CrystEngComm
Volume	18
Issue number	6
DOIs	https://doi.org/10.1039/c5ce01804h
Publication status	Published - 2016

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10.1039/c5ce01804h

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abstract = "The porous structure of a coordination polymer constructed from a Sm(iii) ion and a conformationally flexible ligand is modulated by guest solvent molecules. The coordination polymer containing the guest DMF molecule possesses isolated hydrophobic and hydrophilic voids, while the one containing the guest methanol molecule has a microchannel with alternately arranged hydrophobic-hydrophilic surfaces.",

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AU - Masuya-Suzuki, Atsuko

AU - Matsubara, Nozomi

AU - Karashimada, Ryunosuke

AU - Hoshino, Hitoshi

AU - Iki, Nobuhiko

PY - 2016

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AB - The porous structure of a coordination polymer constructed from a Sm(iii) ion and a conformationally flexible ligand is modulated by guest solvent molecules. The coordination polymer containing the guest DMF molecule possesses isolated hydrophobic and hydrophilic voids, while the one containing the guest methanol molecule has a microchannel with alternately arranged hydrophobic-hydrophilic surfaces.

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Topological modulation of the porous structure of a coordination polymer constructed from a flexible building block via framework-guest interaction during self-assembly

Abstract

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