Topological variation between hexa- and trithiacalix[6]arene-copper(II) complexes: From sphere to wheel by reducing the number of the sulfur bridges

Noriyoshi Kon; Nobuhiko Iki; Takashi Kajiwara; Tasuku Ito; Sotaro Miyano

doi:10.1246/cl.2006.430

Topological variation between hexa- and trithiacalix[6]arene-copper(II) complexes: From sphere to wheel by reducing the number of the sulfur bridges

Noriyoshi Kon, Nobuhiko Iki, Takashi Kajiwara, Tasuku Ito, Sotaro Miyano

ENV - Frontier Science for Advanced Environment

Tohoku University

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Contrary to hexathiacalix[6]arene (H₆L^6S) forming [Cu₁₀-(L^6S)₂]-type spherical decacopper(II) complex, trithiacalix[6]-arene (H₆L^3S), in which three sulfur bridges of H₆L^6S are replaced with methyles in an alternate manner, affords nano-sized wheel-shaped octanuclear complex [Cu ₈(H₂L^3S)₄] consisting of four [Cu₂H₂L^3S] units.

Original language	English
Pages (from-to)	430-431
Number of pages	2
Journal	Chemistry Letters
Volume	35
Issue number	4
DOIs	https://doi.org/10.1246/cl.2006.430
Publication status	Published - 2006 Apr 5

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title = "Topological variation between hexa- and trithiacalix[6]arene-copper(II) complexes: From sphere to wheel by reducing the number of the sulfur bridges",

abstract = "Contrary to hexathiacalix[6]arene (H6L6S) forming [Cu10-(L6S)2]-type spherical decacopper(II) complex, trithiacalix[6]-arene (H6L3S), in which three sulfur bridges of H6L6S are replaced with methyles in an alternate manner, affords nano-sized wheel-shaped octanuclear complex [Cu 8(H2L3S)4] consisting of four [Cu2H2L3S] units.",

author = "Noriyoshi Kon and Nobuhiko Iki and Takashi Kajiwara and Tasuku Ito and Sotaro Miyano",

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AU - Kon, Noriyoshi

AU - Iki, Nobuhiko

AU - Kajiwara, Takashi

AU - Ito, Tasuku

AU - Miyano, Sotaro

PY - 2006/4/5

Y1 - 2006/4/5

N2 - Contrary to hexathiacalix[6]arene (H6L6S) forming [Cu10-(L6S)2]-type spherical decacopper(II) complex, trithiacalix[6]-arene (H6L3S), in which three sulfur bridges of H6L6S are replaced with methyles in an alternate manner, affords nano-sized wheel-shaped octanuclear complex [Cu 8(H2L3S)4] consisting of four [Cu2H2L3S] units.

AB - Contrary to hexathiacalix[6]arene (H6L6S) forming [Cu10-(L6S)2]-type spherical decacopper(II) complex, trithiacalix[6]-arene (H6L3S), in which three sulfur bridges of H6L6S are replaced with methyles in an alternate manner, affords nano-sized wheel-shaped octanuclear complex [Cu 8(H2L3S)4] consisting of four [Cu2H2L3S] units.

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Topological variation between hexa- and trithiacalix[6]arene-copper(II) complexes: From sphere to wheel by reducing the number of the sulfur bridges

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