Total hydrogenation of furan derivatives over silica-supported Ni-Pd alloy catalyst

Yoshinao Nakagawa; Keiichi Tomishige

doi:10.1016/j.catcom.2010.09.003

Total hydrogenation of furan derivatives over silica-supported Ni-Pd alloy catalyst

Yoshinao Nakagawa, Keiichi Tomishige

ENG - Applied Chemistry

Research output: Contribution to journal › Article › peer-review

201 Citations (Scopus)

Abstract

The Ni-Pd bimetallic catalysts supported on silica were prepared by co-impregnation method. The catalyst with Ni/Pd = 7 showed the best catalytic performance for the hydrogenation of 5-hydroxymethyl-2-furaldehyde (HMF). The catalyst was more active than commercial Raney Ni and more selective than Pd/C. The yield of 2,5-bis(hydroxymethyl)tetrahydrofuran reached 96%. Hydrogenation of other furanic compounds, cyclohexanone, phenol, and alkenols also proceeded. Characterizations by TEM and XRD revealed that Ni-Pd alloy particles were formed on Ni-Pd/SiO₂ (Ni/Pd = 7).

Original language	English
Pages (from-to)	154-156
Number of pages	3
Journal	Catalysis Communications
Volume	12
Issue number	3
DOIs	https://doi.org/10.1016/j.catcom.2010.09.003
Publication status	Published - 2010 Nov 3

Keywords

Biomass
Furan derivatives
Hydrogenation
Nickel
Palladium

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Process Chemistry and Technology

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10.1016/j.catcom.2010.09.003

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title = "Total hydrogenation of furan derivatives over silica-supported Ni-Pd alloy catalyst",

abstract = "The Ni-Pd bimetallic catalysts supported on silica were prepared by co-impregnation method. The catalyst with Ni/Pd = 7 showed the best catalytic performance for the hydrogenation of 5-hydroxymethyl-2-furaldehyde (HMF). The catalyst was more active than commercial Raney Ni and more selective than Pd/C. The yield of 2,5-bis(hydroxymethyl)tetrahydrofuran reached 96%. Hydrogenation of other furanic compounds, cyclohexanone, phenol, and alkenols also proceeded. Characterizations by TEM and XRD revealed that Ni-Pd alloy particles were formed on Ni-Pd/SiO2 (Ni/Pd = 7).",

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AU - Nakagawa, Yoshinao

AU - Tomishige, Keiichi

PY - 2010/11/3

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N2 - The Ni-Pd bimetallic catalysts supported on silica were prepared by co-impregnation method. The catalyst with Ni/Pd = 7 showed the best catalytic performance for the hydrogenation of 5-hydroxymethyl-2-furaldehyde (HMF). The catalyst was more active than commercial Raney Ni and more selective than Pd/C. The yield of 2,5-bis(hydroxymethyl)tetrahydrofuran reached 96%. Hydrogenation of other furanic compounds, cyclohexanone, phenol, and alkenols also proceeded. Characterizations by TEM and XRD revealed that Ni-Pd alloy particles were formed on Ni-Pd/SiO2 (Ni/Pd = 7).

AB - The Ni-Pd bimetallic catalysts supported on silica were prepared by co-impregnation method. The catalyst with Ni/Pd = 7 showed the best catalytic performance for the hydrogenation of 5-hydroxymethyl-2-furaldehyde (HMF). The catalyst was more active than commercial Raney Ni and more selective than Pd/C. The yield of 2,5-bis(hydroxymethyl)tetrahydrofuran reached 96%. Hydrogenation of other furanic compounds, cyclohexanone, phenol, and alkenols also proceeded. Characterizations by TEM and XRD revealed that Ni-Pd alloy particles were formed on Ni-Pd/SiO2 (Ni/Pd = 7).

KW - Biomass

KW - Furan derivatives

KW - Hydrogenation

KW - Nickel

KW - Palladium

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JO - Catalysis Communications

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ER -

Total hydrogenation of furan derivatives over silica-supported Ni-Pd alloy catalyst

Abstract

Keywords

ASJC Scopus subject areas

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