Transformation of diols to ketones via intramolecular borrowing hydrogen mechanism

Masazumi Tamura; Takahiro Arai; Yoshinao Nakagawa; Keiichi Tomishige

doi:10.1246/cl.170498

Transformation of diols to ketones via intramolecular borrowing hydrogen mechanism

Masazumi Tamura, Takahiro Arai, Yoshinao Nakagawa, Keiichi Tomishige

ENG - Applied Chemistry

Tohoku University

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Intramolecular borrowing hydrogen methodology composed of dehydrogenation and direct hydrogenolysis is proposed. Rh-MoO_x/SiO₂ substantiated the methodology and acted as an effective catalyst for transformation of diols to the corresponding ketones in water without external hydrogen sources.

Original language	English
Pages (from-to)	1333-1336
Number of pages	4
Journal	Chemistry Letters
Volume	46
Issue number	9
DOIs	https://doi.org/10.1246/cl.170498
Publication status	Published - 2017

Keywords

Diol
Intramolecular borrowing hydrogenation
Ketone

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10.1246/cl.170498

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title = "Transformation of diols to ketones via intramolecular borrowing hydrogen mechanism",

abstract = "Intramolecular borrowing hydrogen methodology composed of dehydrogenation and direct hydrogenolysis is proposed. Rh-MoOx/SiO2 substantiated the methodology and acted as an effective catalyst for transformation of diols to the corresponding ketones in water without external hydrogen sources.",

keywords = "Diol, Intramolecular borrowing hydrogenation, Ketone",

author = "Masazumi Tamura and Takahiro Arai and Yoshinao Nakagawa and Keiichi Tomishige",

note = "Funding Information: This work was supported by JSPS KAKENHI Grant Number JP26249121. Publisher Copyright: {\textcopyright} 2017 The Chemical Society of Japan.",

year = "2017",

doi = "10.1246/cl.170498",

language = "English",

volume = "46",

pages = "1333--1336",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "The Chemical Society of Japan",

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TY - JOUR

T1 - Transformation of diols to ketones via intramolecular borrowing hydrogen mechanism

AU - Tamura, Masazumi

AU - Arai, Takahiro

AU - Nakagawa, Yoshinao

AU - Tomishige, Keiichi

PY - 2017

Y1 - 2017

N2 - Intramolecular borrowing hydrogen methodology composed of dehydrogenation and direct hydrogenolysis is proposed. Rh-MoOx/SiO2 substantiated the methodology and acted as an effective catalyst for transformation of diols to the corresponding ketones in water without external hydrogen sources.

AB - Intramolecular borrowing hydrogen methodology composed of dehydrogenation and direct hydrogenolysis is proposed. Rh-MoOx/SiO2 substantiated the methodology and acted as an effective catalyst for transformation of diols to the corresponding ketones in water without external hydrogen sources.

KW - Diol

KW - Intramolecular borrowing hydrogenation

KW - Ketone

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U2 - 10.1246/cl.170498

DO - 10.1246/cl.170498

M3 - Article

AN - SCOPUS:85026896702

SN - 0366-7022

VL - 46

SP - 1333

EP - 1336

JO - Chemistry Letters

JF - Chemistry Letters

IS - 9

ER -

Transformation of diols to ketones via intramolecular borrowing hydrogen mechanism

Abstract

Keywords

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