Tuning of intramolecular π-π overlap mode of tetrathiafulvalene bisannulated macrocycles in the open-shell electronic state

Tomoyuki Akutagawa; Yukako Abe; Tatsuo Hasegawa; Takayoshi Nakamura; Tamotsu Inabe; Christian A. Christensen; Jan Becher

doi:10.1246/cl.2000.132

Tuning of intramolecular π-π overlap mode of tetrathiafulvalene bisannulated macrocycles in the open-shell electronic state

Tomoyuki Akutagawa, Yukako Abe, Tatsuo Hasegawa, Takayoshi Nakamura, Tamotsu Inabe, Christian A. Christensen, Jan Becher

IMRAM - Materials-Measurement Hybrid Research Center

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Charge-transfer complexes of bis(methylthio)tetrathiafulvalene (DMT-TTF) bisannulated macrocycles with 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F₄-TCNQ) were prepared. The crystal structural analysis revealed an intramolecular dimer structure with the π-π overlap of DMT-TTF units. The magnitude of intramolecular π-π overlap depends on the ring size of macrocycles.

Original language	English
Pages (from-to)	132-133
Number of pages	2
Journal	Chemistry Letters
Issue number	2
DOIs	https://doi.org/10.1246/cl.2000.132
Publication status	Published - 2000

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10.1246/cl.2000.132

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abstract = "Charge-transfer complexes of bis(methylthio)tetrathiafulvalene (DMT-TTF) bisannulated macrocycles with 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F4-TCNQ) were prepared. The crystal structural analysis revealed an intramolecular dimer structure with the π-π overlap of DMT-TTF units. The magnitude of intramolecular π-π overlap depends on the ring size of macrocycles.",

author = "Tomoyuki Akutagawa and Yukako Abe and Tatsuo Hasegawa and Takayoshi Nakamura and Tamotsu Inabe and Christensen, {Christian A.} and Jan Becher",

year = "2000",

doi = "10.1246/cl.2000.132",

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journal = "Chemistry Letters",

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T1 - Tuning of intramolecular π-π overlap mode of tetrathiafulvalene bisannulated macrocycles in the open-shell electronic state

AU - Akutagawa, Tomoyuki

AU - Abe, Yukako

AU - Hasegawa, Tatsuo

AU - Nakamura, Takayoshi

AU - Inabe, Tamotsu

AU - Christensen, Christian A.

AU - Becher, Jan

PY - 2000

Y1 - 2000

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AB - Charge-transfer complexes of bis(methylthio)tetrathiafulvalene (DMT-TTF) bisannulated macrocycles with 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F4-TCNQ) were prepared. The crystal structural analysis revealed an intramolecular dimer structure with the π-π overlap of DMT-TTF units. The magnitude of intramolecular π-π overlap depends on the ring size of macrocycles.

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JO - Chemistry Letters

JF - Chemistry Letters

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ER -

Tuning of intramolecular π-π overlap mode of tetrathiafulvalene bisannulated macrocycles in the open-shell electronic state

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