Ultrasonic approach to obtaining partial thermodynamic characteristics of solutions

Dmitry A. Tikhonov; Oleg E. Kiselyov; Armen P. Sarvazyan; Gari N. Sarkisov

doi:10.1016/0041-624X(95)00053-6

Ultrasonic approach to obtaining partial thermodynamic characteristics of solutions

Dmitry A. Tikhonov, Oleg E. Kiselyov, Armen P. Sarvazyan, Gari N. Sarkisov

INF - Computer and Mathematical Sciences

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

We describe a method for evaluating the thermodynamic characteristics both of pure liquids and of solutes in solutions using data derived from ultrasonic velocity measurements. The principal possibility of using ultrasound velocity lies in the fact that the velocity of ultrasound is a simple function of the adiabatic compressibility. The problem is formulated as an initial value problem for the parabolic type differential equations in partial derivatives. The validity of the method is demonstrated by calculation of the thermodynamic parameters for water, glycine and alanine in aqueous solutions at infinite dilution.

Original language	English
Pages (from-to)	301-310
Number of pages	10
Journal	Ultrasonics
Volume	33
Issue number	4
DOIs	https://doi.org/10.1016/0041-624X(95)00053-6
Publication status	Published - 1995 Jul

Keywords

compressibility
equation of state
partial thermodynamic characteristics
velocity of ultrasound

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10.1016/0041-624X(95)00053-6

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title = "Ultrasonic approach to obtaining partial thermodynamic characteristics of solutions",

abstract = "We describe a method for evaluating the thermodynamic characteristics both of pure liquids and of solutes in solutions using data derived from ultrasonic velocity measurements. The principal possibility of using ultrasound velocity lies in the fact that the velocity of ultrasound is a simple function of the adiabatic compressibility. The problem is formulated as an initial value problem for the parabolic type differential equations in partial derivatives. The validity of the method is demonstrated by calculation of the thermodynamic parameters for water, glycine and alanine in aqueous solutions at infinite dilution.",

keywords = "compressibility, equation of state, partial thermodynamic characteristics, velocity of ultrasound",

author = "Tikhonov, {Dmitry A.} and Kiselyov, {Oleg E.} and Sarvazyan, {Armen P.} and Sarkisov, {Gari N.}",

note = "Funding Information: The authors wish to thank Dr D.P. Kharakoz, Dr T.V. Chalikian, and Professor K.J. Breslauer for valuable discussions and helpful comments. This work was partly supported by National Institute of Health Grants GM23509, GM34469 and CA47995.",

year = "1995",

month = jul,

doi = "10.1016/0041-624X(95)00053-6",

language = "English",

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pages = "301--310",

journal = "Ultrasonics",

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TY - JOUR

T1 - Ultrasonic approach to obtaining partial thermodynamic characteristics of solutions

AU - Tikhonov, Dmitry A.

AU - Kiselyov, Oleg E.

AU - Sarvazyan, Armen P.

AU - Sarkisov, Gari N.

N1 - Funding Information: The authors wish to thank Dr D.P. Kharakoz, Dr T.V. Chalikian, and Professor K.J. Breslauer for valuable discussions and helpful comments. This work was partly supported by National Institute of Health Grants GM23509, GM34469 and CA47995.

PY - 1995/7

Y1 - 1995/7

N2 - We describe a method for evaluating the thermodynamic characteristics both of pure liquids and of solutes in solutions using data derived from ultrasonic velocity measurements. The principal possibility of using ultrasound velocity lies in the fact that the velocity of ultrasound is a simple function of the adiabatic compressibility. The problem is formulated as an initial value problem for the parabolic type differential equations in partial derivatives. The validity of the method is demonstrated by calculation of the thermodynamic parameters for water, glycine and alanine in aqueous solutions at infinite dilution.

AB - We describe a method for evaluating the thermodynamic characteristics both of pure liquids and of solutes in solutions using data derived from ultrasonic velocity measurements. The principal possibility of using ultrasound velocity lies in the fact that the velocity of ultrasound is a simple function of the adiabatic compressibility. The problem is formulated as an initial value problem for the parabolic type differential equations in partial derivatives. The validity of the method is demonstrated by calculation of the thermodynamic parameters for water, glycine and alanine in aqueous solutions at infinite dilution.

KW - compressibility

KW - equation of state

KW - partial thermodynamic characteristics

KW - velocity of ultrasound

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U2 - 10.1016/0041-624X(95)00053-6

DO - 10.1016/0041-624X(95)00053-6

M3 - Article

C2 - 7491739

AN - SCOPUS:0029330350

SN - 0041-624X

VL - 33

SP - 301

EP - 310

JO - Ultrasonics

JF - Ultrasonics

IS - 4

ER -

Ultrasonic approach to obtaining partial thermodynamic characteristics of solutions

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Keywords

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