Unexpected dehomologation of primary alcohols to one-carbon shorter carboxylic acids using o-iodoxybenzoic acid (IBX)

Shu Xu; Kaori Itto; Masahide Satoh; Hirokazu Arimoto

doi:10.1039/c3cc49160a

Unexpected dehomologation of primary alcohols to one-carbon shorter carboxylic acids using o-iodoxybenzoic acid (IBX)

Shu Xu, Kaori Itto, Masahide Satoh, Hirokazu Arimoto

LIF - Molecular and Chemical Life Science

Tohoku University

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

A novel and efficient transformation of primary alcohols to one-carbon shorter carboxylic acids using IBX is reported. Mechanistic studies revealed that the combination of IBX and molecular iodine produces a different active hypervalent iodine species.

Original language	English
Pages (from-to)	2758-2761
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	21
DOIs	https://doi.org/10.1039/c3cc49160a
Publication status	Published - 2014 Feb 13

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title = "Unexpected dehomologation of primary alcohols to one-carbon shorter carboxylic acids using o-iodoxybenzoic acid (IBX)",

abstract = "A novel and efficient transformation of primary alcohols to one-carbon shorter carboxylic acids using IBX is reported. Mechanistic studies revealed that the combination of IBX and molecular iodine produces a different active hypervalent iodine species.",

author = "Shu Xu and Kaori Itto and Masahide Satoh and Hirokazu Arimoto",

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AU - Arimoto, Hirokazu

PY - 2014/2/13

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Unexpected dehomologation of primary alcohols to one-carbon shorter carboxylic acids using o-iodoxybenzoic acid (IBX)

Abstract

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