Unexpected formation of a sterically protected nitrogen pentasulfide ArNS5 (Ar = 2,6-dimesityl-4-methylphenyl) and the X-ray crystallographic analysis

Shigeru Sasaki; Hiroya Hatsushiba; Masaaki Yoshifuji

doi:10.1039/a805235b

Unexpected formation of a sterically protected nitrogen pentasulfide ArNS₅ (Ar = 2,6-dimesityl-4-methylphenyl) and the X-ray crystallographic analysis

Shigeru Sasaki, Hiroya Hatsushiba, Masaaki Yoshifuji

SCI - Chemistry

Tohoku University

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

A stable cyclic nitrogen pentasulfide ArNS₅ (Ar = 2,6-dimesityl-4-methylphenyl) was unexpectedly obtained by passing the corresponding N-thiosulfinylaniline through a silica gel column and the chair form of the six-membered ring was revealed by X-ray crystallographic analysis.

Original language	English
Pages (from-to)	2221-2222
Number of pages	2
Journal	Chemical Communications
Issue number	20
DOIs	https://doi.org/10.1039/a805235b
Publication status	Published - 1998 Oct 21

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abstract = "A stable cyclic nitrogen pentasulfide ArNS5 (Ar = 2,6-dimesityl-4-methylphenyl) was unexpectedly obtained by passing the corresponding N-thiosulfinylaniline through a silica gel column and the chair form of the six-membered ring was revealed by X-ray crystallographic analysis.",

author = "Shigeru Sasaki and Hiroya Hatsushiba and Masaaki Yoshifuji",

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AU - Sasaki, Shigeru

AU - Hatsushiba, Hiroya

AU - Yoshifuji, Masaaki

PY - 1998/10/21

Y1 - 1998/10/21

N2 - A stable cyclic nitrogen pentasulfide ArNS5 (Ar = 2,6-dimesityl-4-methylphenyl) was unexpectedly obtained by passing the corresponding N-thiosulfinylaniline through a silica gel column and the chair form of the six-membered ring was revealed by X-ray crystallographic analysis.

AB - A stable cyclic nitrogen pentasulfide ArNS5 (Ar = 2,6-dimesityl-4-methylphenyl) was unexpectedly obtained by passing the corresponding N-thiosulfinylaniline through a silica gel column and the chair form of the six-membered ring was revealed by X-ray crystallographic analysis.

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JF - Chemical Communications

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Unexpected formation of a sterically protected nitrogen pentasulfide ArNS₅ (Ar = 2,6-dimesityl-4-methylphenyl) and the X-ray crystallographic analysis

Abstract

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