@article{2a72727068ad4be5864a7655e1ce6fbd,
title = "Unexpected reversal of stereochemistry observed in the addition of methallyltrimethylsilane to a chiral α-keto imide",
abstract = "A Lewis acid promoted nucleophilic addition of methallyltrimethylsilane to a chiral a-keto imide proceeded with stereoselectivity opposite to that predicted from Soai's report. The difference in the structure of a-keto imides between Soai's and our cases might have affected the diastereofacial selectivity.",
keywords = "reversal of stereochemistry, α-hydroxycarboxylic acid, α-keto imide",
author = "Sayaka Ishii and Katsuya Saito and Shigefumi Kuwahara and Masaru Enomoto",
note = "Funding Information: This work was financially supported by JSPS KAKENHI (Grant No. 19K05837), JSPS Core-to-Core Program (Advanced Research Networks) entitled “Establishment of international agricultural immunology research-core for a quantum improvement in food safety,” and AMED (Grant No. JP19am0101100). Publisher Copyright: {\textcopyright} The Author(s) 2021. Published by Oxford University Press on behalf of Japan Society for Bioscience, Biotechnology, and Agrochemistry. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.",
year = "2021",
month = mar,
day = "1",
doi = "10.1093/bbb/zbaa086",
language = "English",
volume = "85",
pages = "488--492",
journal = "Bioscience, Biotechnology and Biochemistry",
issn = "0916-8451",
publisher = "Oxford University Press",
number = "3",
}