Unprecedented soliton formation mechanism in quasi-one-dimensional chloro-bridged PtII-PtIV mixed-valence compound, {[Pt(en)2][PtCl2(en)2]}3(CuCl 4)4·12H2O

Masahiro Yamashita; Hidemitsu Aso; Satoshi Matsunaga; Koichi Takizawa; Kazuya Nakata; Chihiro Kachi-Terajima; Fumiyasu Iwahori; Tomohiko Ishii; Hitoshi Miyasaka; Ken Ichi Sugiura; Takuya Kawashima; Kenzi Takai; Noritaka Kuroda; Motoo Shiro; Hideo Kishida; Hiroshi Okamoto; Hiroyuki Takahashi; Hisaaki Tanaka; Kazuhiro Marumoto; Shin Ichi Kuroda

doi:10.1246/cl.2003.278

Unprecedented soliton formation mechanism in quasi-one-dimensional chloro-bridged Pt^II-Pt^IV mixed-valence compound, {[Pt(en)₂][PtCl₂(en)₂]}₃(CuCl ₄)₄·12H₂O

Masahiro Yamashita, Hidemitsu Aso, Satoshi Matsunaga, Koichi Takizawa, Kazuya Nakata, Chihiro Kachi-Terajima, Fumiyasu Iwahori, Tomohiko Ishii, Hitoshi Miyasaka, Ken Ichi Sugiura, Takuya Kawashima, Kenzi Takai, Noritaka Kuroda, Motoo Shiro, Hideo Kishida, Hiroshi Okamoto, Hiroyuki Takahashi, Hisaaki Tanaka, Kazuhiro Marumoto, Shin Ichi Kuroda

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

A new type of complex consisting of double liner-chain structure {[Pt(en)₂][PtCl₂(en)₂]}₃(CuCl ₄)₄·12H₂O was synthesized. High concentration (ca. 200 times larger than the literature) of neutral soliton (Pt^III component) formation was found. This unprecedented soliton formation mechanism will be discussed.

Original language	English
Pages (from-to)	278-279
Number of pages	2
Journal	Chemistry Letters
Volume	32
Issue number	3
DOIs	https://doi.org/10.1246/cl.2003.278
Publication status	Published - 2003 Mar 5
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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Yamashita, M., Aso, H., Matsunaga, S., Takizawa, K., Nakata, K., Kachi-Terajima, C., Iwahori, F., Ishii, T., Miyasaka, H., Sugiura, K. I., Kawashima, T., Takai, K., Kuroda, N., Shiro, M., Kishida, H., Okamoto, H., Takahashi, H., Tanaka, H., Marumoto, K., & Kuroda, S. I. (2003). Unprecedented soliton formation mechanism in quasi-one-dimensional chloro-bridged Pt^II-Pt^IV mixed-valence compound, {[Pt(en)₂][PtCl₂(en)₂]}₃(CuCl ₄)₄·12H₂O. Chemistry Letters, 32(3), 278-279. https://doi.org/10.1246/cl.2003.278

Yamashita, M, Aso, H, Matsunaga, S, Takizawa, K, Nakata, K, Kachi-Terajima, C, Iwahori, F, Ishii, T, Miyasaka, H, Sugiura, KI, Kawashima, T, Takai, K, Kuroda, N, Shiro, M, Kishida, H, Okamoto, H, Takahashi, H, Tanaka, H, Marumoto, K & Kuroda, SI 2003, 'Unprecedented soliton formation mechanism in quasi-one-dimensional chloro-bridged Pt^II-Pt^IV mixed-valence compound, {[Pt(en)₂][PtCl₂(en)₂]}₃(CuCl ₄)₄·12H₂O', Chemistry Letters, vol. 32, no. 3, pp. 278-279. https://doi.org/10.1246/cl.2003.278

@article{a0e8b8a5ca974b5aa4f3ef6158adb627,

title = "Unprecedented soliton formation mechanism in quasi-one-dimensional chloro-bridged PtII-PtIV mixed-valence compound, {[Pt(en)2][PtCl2(en)2]}3(CuCl 4)4·12H2O",

abstract = "A new type of complex consisting of double liner-chain structure {[Pt(en)2][PtCl2(en)2]}3(CuCl 4)4·12H2O was synthesized. High concentration (ca. 200 times larger than the literature) of neutral soliton (PtIII component) formation was found. This unprecedented soliton formation mechanism will be discussed.",

author = "Masahiro Yamashita and Hidemitsu Aso and Satoshi Matsunaga and Koichi Takizawa and Kazuya Nakata and Chihiro Kachi-Terajima and Fumiyasu Iwahori and Tomohiko Ishii and Hitoshi Miyasaka and Sugiura, {Ken Ichi} and Takuya Kawashima and Kenzi Takai and Noritaka Kuroda and Motoo Shiro and Hideo Kishida and Hiroshi Okamoto and Hiroyuki Takahashi and Hisaaki Tanaka and Kazuhiro Marumoto and Kuroda, {Shin Ichi}",

year = "2003",

month = mar,

day = "5",

doi = "10.1246/cl.2003.278",

language = "English",

volume = "32",

pages = "278--279",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Chemical Society of Japan",

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TY - JOUR

T1 - Unprecedented soliton formation mechanism in quasi-one-dimensional chloro-bridged PtII-PtIV mixed-valence compound, {[Pt(en)2][PtCl2(en)2]}3(CuCl 4)4·12H2O

AU - Yamashita, Masahiro

AU - Aso, Hidemitsu

AU - Matsunaga, Satoshi

AU - Takizawa, Koichi

AU - Nakata, Kazuya

AU - Kachi-Terajima, Chihiro

AU - Iwahori, Fumiyasu

AU - Ishii, Tomohiko

AU - Miyasaka, Hitoshi

AU - Sugiura, Ken Ichi

AU - Kawashima, Takuya

AU - Takai, Kenzi

AU - Kuroda, Noritaka

AU - Shiro, Motoo

AU - Kishida, Hideo

AU - Okamoto, Hiroshi

AU - Takahashi, Hiroyuki

AU - Tanaka, Hisaaki

AU - Marumoto, Kazuhiro

AU - Kuroda, Shin Ichi

PY - 2003/3/5

Y1 - 2003/3/5

N2 - A new type of complex consisting of double liner-chain structure {[Pt(en)2][PtCl2(en)2]}3(CuCl 4)4·12H2O was synthesized. High concentration (ca. 200 times larger than the literature) of neutral soliton (PtIII component) formation was found. This unprecedented soliton formation mechanism will be discussed.

AB - A new type of complex consisting of double liner-chain structure {[Pt(en)2][PtCl2(en)2]}3(CuCl 4)4·12H2O was synthesized. High concentration (ca. 200 times larger than the literature) of neutral soliton (PtIII component) formation was found. This unprecedented soliton formation mechanism will be discussed.

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DO - 10.1246/cl.2003.278

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JO - Chemistry Letters

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Unprecedented soliton formation mechanism in quasi-one-dimensional chloro-bridged Pt^II-Pt^IV mixed-valence compound, {[Pt(en)₂][PtCl₂(en)₂]}₃(CuCl ₄)₄·12H₂O

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