Abstract
A new 2D-ACAR apparatus has been developed. A pair of compact position-sensitive γ-ray detectors are used, each of which consist of 2.2 × 2.2 × 15 mm3 BGO scintillator blocks bunched into a 25 × 21 array with 2.4 mm pich, and coupled to a position-sensitive photomultiplier tube. The new apparatus has been applied to study the wave functions of the delocalized positronium(Ps) in alkali halides and the localized Ps in complex salt [Zn(ptz)6](BF4)2. It has been observed that all the Bloch Ps satellite peaks in KCl and KI, except for the [200] peaks, are extremely weak. The anisotropies of the Ps wave function in [Zn(ptz)6](BF4)2 changes near the temperature where the Fe analogue of the complex salt exibits spin-crossover transition.
Original language | English |
---|---|
Pages (from-to) | 488-490 |
Number of pages | 3 |
Journal | Materials Science Forum |
Volume | 255-257 |
DOIs | |
Publication status | Published - 1997 |
Keywords
- 2D-ACAR
- Alkali Halide
- Complex Salt
- KCI
- KI
- Position Sensitive Detector
- Positronium
- Spin-Crossover
- [Fe(ptz)](BF)
- [zn(ptz)](BF)