Valence-modulation-induced optical nonlinearity of intermolecular charge-transfer Langmuir-Blodgett films

Tatsuo Hasegawa; Tomoyuki Akutagawa; Taro Konuma; Takayoshi Nakamura; Jun Kawamata; Kuon Inoue

Valence-modulation-induced optical nonlinearity of intermolecular charge-transfer Langmuir-Blodgett films

Tatsuo Hasegawa, Tomoyuki Akutagawa, Taro Konuma, Takayoshi Nakamura, Jun Kawamata, Kuon Inoue

IMRAM - Materials-Measurement Hybrid Research Center

Hokkaido University

Research output: Contribution to journal › Conference article › peer-review

1 Citation (Scopus)

Abstract

Second-order nonlinear optical properties are investigated for Langmuir-Blodgett (LB) films of charge-transfer complexes having non-centro-symmetrical molecular arrangements. The films exhibit large linear electro-optic effect (Im[χ⁽²⁾(-ω; ω, 0)] approx. 0.3 pm/V) in photon energy range of intramolecular transition, while component molecules have no permanent dipoles inside the molecules. The observed features in Im[χ⁽²⁾] spectra are discussed in terms of the electric-field-induced valence modulation effect on the intramolecular π-π^* excitation of donor and acceptor molecules.

Original language	English
Pages (from-to)	143-146
Number of pages	4
Journal	Molecular Crystals and Liquid Crystals Science and Technology Section B: Nonlinear Optics
Volume	22
Issue number	1-4
Publication status	Published - 1999
Event	Proceedings of the 1998 4th International Conference on Organic Nonlinear Optics (ICONO'4) - The 8th IKETANI Conference - Chitose, Jpn Duration: 1998 Oct 12 → 1998 Oct 15

Cite this

@article{5ee35fb9ddcb4e4592e664ad83919745,

title = "Valence-modulation-induced optical nonlinearity of intermolecular charge-transfer Langmuir-Blodgett films",

abstract = "Second-order nonlinear optical properties are investigated for Langmuir-Blodgett (LB) films of charge-transfer complexes having non-centro-symmetrical molecular arrangements. The films exhibit large linear electro-optic effect (Im[χ(2)(-ω; ω, 0)] approx. 0.3 pm/V) in photon energy range of intramolecular transition, while component molecules have no permanent dipoles inside the molecules. The observed features in Im[χ(2)] spectra are discussed in terms of the electric-field-induced valence modulation effect on the intramolecular π-π* excitation of donor and acceptor molecules.",

author = "Tatsuo Hasegawa and Tomoyuki Akutagawa and Taro Konuma and Takayoshi Nakamura and Jun Kawamata and Kuon Inoue",

year = "1999",

language = "English",

volume = "22",

pages = "143--146",

journal = "Molecular Crystals and Liquid Crystals Science and Technology Section B: Nonlinear Optics",

issn = "1058-7268",

publisher = "Old City Publishing",

number = "1-4",

note = "Proceedings of the 1998 4th International Conference on Organic Nonlinear Optics (ICONO'4) - The 8th IKETANI Conference ; Conference date: 12-10-1998 Through 15-10-1998",

}

Valence-modulation-induced optical nonlinearity of intermolecular charge-transfer Langmuir-Blodgett films. / Hasegawa, Tatsuo; Akutagawa, Tomoyuki; Konuma, Taro et al.
In: Molecular Crystals and Liquid Crystals Science and Technology Section B: Nonlinear Optics, Vol. 22, No. 1-4, 1999, p. 143-146.

Research output: Contribution to journal › Conference article › peer-review

TY - JOUR

T1 - Valence-modulation-induced optical nonlinearity of intermolecular charge-transfer Langmuir-Blodgett films

AU - Hasegawa, Tatsuo

AU - Akutagawa, Tomoyuki

AU - Konuma, Taro

AU - Nakamura, Takayoshi

AU - Kawamata, Jun

AU - Inoue, Kuon

PY - 1999

Y1 - 1999

N2 - Second-order nonlinear optical properties are investigated for Langmuir-Blodgett (LB) films of charge-transfer complexes having non-centro-symmetrical molecular arrangements. The films exhibit large linear electro-optic effect (Im[χ(2)(-ω; ω, 0)] approx. 0.3 pm/V) in photon energy range of intramolecular transition, while component molecules have no permanent dipoles inside the molecules. The observed features in Im[χ(2)] spectra are discussed in terms of the electric-field-induced valence modulation effect on the intramolecular π-π* excitation of donor and acceptor molecules.

AB - Second-order nonlinear optical properties are investigated for Langmuir-Blodgett (LB) films of charge-transfer complexes having non-centro-symmetrical molecular arrangements. The films exhibit large linear electro-optic effect (Im[χ(2)(-ω; ω, 0)] approx. 0.3 pm/V) in photon energy range of intramolecular transition, while component molecules have no permanent dipoles inside the molecules. The observed features in Im[χ(2)] spectra are discussed in terms of the electric-field-induced valence modulation effect on the intramolecular π-π* excitation of donor and acceptor molecules.

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M3 - Conference article

AN - SCOPUS:0033352422

SN - 1058-7268

VL - 22

SP - 143

EP - 146

JO - Molecular Crystals and Liquid Crystals Science and Technology Section B: Nonlinear Optics

JF - Molecular Crystals and Liquid Crystals Science and Technology Section B: Nonlinear Optics

IS - 1-4

T2 - Proceedings of the 1998 4th International Conference on Organic Nonlinear Optics (ICONO'4) - The 8th IKETANI Conference

Y2 - 12 October 1998 through 15 October 1998

ER -

Valence-modulation-induced optical nonlinearity of intermolecular charge-transfer Langmuir-Blodgett films

Abstract

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