Vapochromic behavior accompanied by phase transition between charge-polarization and charge-density-wave states in a quasi-one-dimensional iodine-bridged dinuclear platinum compound

Hiroyuki Mastuzaki; Hideo Kishida; Hiroshi Okamoto; Kouichi Takizawa; Satoshi Matsunaga; Shinya Takaishi; Hitoshi Miyasaka; Ken Ichi Sugiura; Masahiro Yamashita

doi:10.1002/anie.200500091

Vapochromic behavior accompanied by phase transition between charge-polarization and charge-density-wave states in a quasi-one-dimensional iodine-bridged dinuclear platinum compound

Hiroyuki Mastuzaki, Hideo Kishida, Hiroshi Okamoto, Kouichi Takizawa, Satoshi Matsunaga, Shinya Takaishi, Hitoshi Miyasaka, Ken Ichi Sugiura, Masahiro Yamashita

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

(Figure Presented) Color sense: A reversible phase transition occurs with a change in color and structural properties on exposure to water vapor of the 1D halogen-bridged dinuclear platinum compound [NH₃(C₄H ₈)NH₃]_2- [Pt₂(pop) ₄I]·4 H₂O (pop=P₂O₅H ₂^2-; see microscope images in reflection mode). This transition takes place between a paramagnetic charge-polarization state (296 K) and a diamagnetic charge-density-wave state (340 K).

Original language	English
Pages (from-to)	3240-3243
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	44
Issue number	21
DOIs	https://doi.org/10.1002/anie.200500091
Publication status	Published - 2005 May 20

Keywords

Chain structures
Phase transitions
Platinum raman spectroscopy
Vapochromism

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10.1002/anie.200500091

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Mastuzaki, H., Kishida, H., Okamoto, H., Takizawa, K., Matsunaga, S., Takaishi, S., Miyasaka, H., Sugiura, K. I., & Yamashita, M. (2005). Vapochromic behavior accompanied by phase transition between charge-polarization and charge-density-wave states in a quasi-one-dimensional iodine-bridged dinuclear platinum compound. Angewandte Chemie - International Edition, 44(21), 3240-3243. https://doi.org/10.1002/anie.200500091

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title = "Vapochromic behavior accompanied by phase transition between charge-polarization and charge-density-wave states in a quasi-one-dimensional iodine-bridged dinuclear platinum compound",

abstract = "(Figure Presented) Color sense: A reversible phase transition occurs with a change in color and structural properties on exposure to water vapor of the 1D halogen-bridged dinuclear platinum compound [NH3(C4H 8)NH3]2- [Pt2(pop) 4I]·4 H2O (pop=P2O5H 22-; see microscope images in reflection mode). This transition takes place between a paramagnetic charge-polarization state (296 K) and a diamagnetic charge-density-wave state (340 K).",

keywords = "Chain structures, Phase transitions, Platinum raman spectroscopy, Vapochromism",

author = "Hiroyuki Mastuzaki and Hideo Kishida and Hiroshi Okamoto and Kouichi Takizawa and Satoshi Matsunaga and Shinya Takaishi and Hitoshi Miyasaka and Sugiura, {Ken Ichi} and Masahiro Yamashita",

year = "2005",

month = may,

day = "20",

doi = "10.1002/anie.200500091",

language = "English",

volume = "44",

pages = "3240--3243",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

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}

Mastuzaki, H, Kishida, H, Okamoto, H, Takizawa, K, Matsunaga, S, Takaishi, S , Miyasaka, H, Sugiura, KI & Yamashita, M 2005, 'Vapochromic behavior accompanied by phase transition between charge-polarization and charge-density-wave states in a quasi-one-dimensional iodine-bridged dinuclear platinum compound', Angewandte Chemie - International Edition, vol. 44, no. 21, pp. 3240-3243. https://doi.org/10.1002/anie.200500091

Vapochromic behavior accompanied by phase transition between charge-polarization and charge-density-wave states in a quasi-one-dimensional iodine-bridged dinuclear platinum compound. / Mastuzaki, Hiroyuki; Kishida, Hideo; Okamoto, Hiroshi et al.
In: Angewandte Chemie - International Edition, Vol. 44, No. 21, 20.05.2005, p. 3240-3243.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Vapochromic behavior accompanied by phase transition between charge-polarization and charge-density-wave states in a quasi-one-dimensional iodine-bridged dinuclear platinum compound

AU - Mastuzaki, Hiroyuki

AU - Kishida, Hideo

AU - Okamoto, Hiroshi

AU - Takizawa, Kouichi

AU - Matsunaga, Satoshi

AU - Takaishi, Shinya

AU - Miyasaka, Hitoshi

AU - Sugiura, Ken Ichi

AU - Yamashita, Masahiro

PY - 2005/5/20

Y1 - 2005/5/20

N2 - (Figure Presented) Color sense: A reversible phase transition occurs with a change in color and structural properties on exposure to water vapor of the 1D halogen-bridged dinuclear platinum compound [NH3(C4H 8)NH3]2- [Pt2(pop) 4I]·4 H2O (pop=P2O5H 22-; see microscope images in reflection mode). This transition takes place between a paramagnetic charge-polarization state (296 K) and a diamagnetic charge-density-wave state (340 K).

AB - (Figure Presented) Color sense: A reversible phase transition occurs with a change in color and structural properties on exposure to water vapor of the 1D halogen-bridged dinuclear platinum compound [NH3(C4H 8)NH3]2- [Pt2(pop) 4I]·4 H2O (pop=P2O5H 22-; see microscope images in reflection mode). This transition takes place between a paramagnetic charge-polarization state (296 K) and a diamagnetic charge-density-wave state (340 K).

KW - Chain structures

KW - Phase transitions

KW - Platinum raman spectroscopy

KW - Vapochromism

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Vapochromic behavior accompanied by phase transition between charge-polarization and charge-density-wave states in a quasi-one-dimensional iodine-bridged dinuclear platinum compound

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