Abstract
The density, viscosity and thermal conductivity values are reported for a series of 1-alkyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl] amide compounds, where the alkyl group is butyl ([BMIM][NTf2]), hexyl ([HMIM][NTf2]), or octyl ([OMIM][NTf2]). The densities were measured with a vibrating tube densimeter over the temperature range 293-353 K at pressures up to 20 MPa. The estimated combined standard uncertainty was 0.1%. The viscosities were measured using a rolling-ball viscometer over the temperature range 293-353 K, at pressures up to 20 MPa. The combined standard uncertainty in the viscosity was estimated to be 1.6%. The experimental values were correlated with a hybrid Vogel-Fulcher-Tammann/Tait equation. The thermal conductivities were measured using the transient short hot-wire method over the temperature range 294-354 K, at 0.1 MPa. The combined standard uncertainty in the thermal conductivity was estimated to be 2.2%.
Original language | English |
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Pages (from-to) | 231-245 |
Number of pages | 15 |
Journal | High Temperatures - High Pressures |
Volume | 46 |
Issue number | 3 |
Publication status | Published - 2017 |
Keywords
- Density
- High pressure
- Ionic liquid
- Reference ionic liquid
- Thermal conductivity
- Transient short hot-wire method
- Viscosity
ASJC Scopus subject areas
- Condensed Matter Physics
- Mechanics of Materials
- Physical and Theoretical Chemistry