Voltammetric response of ferroceneboronic acid to diol and phenolic compounds as possible pollutants

Shigehiro Takahashi; Naoyuki Abiko; Nobuhiro Haraguchi; Hiroyuki Fujita; Eriko Seki; Tetsuya Ono; Kentaro Yoshida; Jun ichi Anzai

doi:10.1016/S1001-0742(10)60509-8

Voltammetric response of ferroceneboronic acid to diol and phenolic compounds as possible pollutants

Shigehiro Takahashi, Naoyuki Abiko, Nobuhiro Haraguchi, Hiroyuki Fujita, Eriko Seki, Tetsuya Ono, Kentaro Yoshida, Jun ichi Anzai

PHA - Molecular Pharmaceutical Science

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

A voltammetric determination of possible organic pollutants such as diol and phenolic compounds in water was studied using ferroceneboronic acid (FBA) as a redox-active marker. A cyclic voltammogram of FBA exhibited a pair of oxidation and reduction peaks at 230 and 170 mV at pH 7.0, respectively, while another pair of redox peaks was observed in the presence of diol or phenolic compounds tested. The results were rationalized based on the formation of boronate esters of FBA with the added compounds. The changes in the redox peak currents were dependent on the concentration of the additives, suggesting a usefulness of FBA in the electrochemical determination of these compounds in water.

Original language	English
Pages (from-to)	1027-1032
Number of pages	6
Journal	Journal of Environmental Sciences
Volume	23
Issue number	6
DOIs	https://doi.org/10.1016/S1001-0742(10)60509-8
Publication status	Published - 2011 Jun

Keywords

Cyclic voltammetry
Electrochemical determination
Ferroceneboronic acid
Phenolic compound
Pollutants in water
Sugar

ASJC Scopus subject areas

Environmental Engineering
Environmental Chemistry
Environmental Science(all)

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10.1016/S1001-0742(10)60509-8

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title = "Voltammetric response of ferroceneboronic acid to diol and phenolic compounds as possible pollutants",

abstract = "A voltammetric determination of possible organic pollutants such as diol and phenolic compounds in water was studied using ferroceneboronic acid (FBA) as a redox-active marker. A cyclic voltammogram of FBA exhibited a pair of oxidation and reduction peaks at 230 and 170 mV at pH 7.0, respectively, while another pair of redox peaks was observed in the presence of diol or phenolic compounds tested. The results were rationalized based on the formation of boronate esters of FBA with the added compounds. The changes in the redox peak currents were dependent on the concentration of the additives, suggesting a usefulness of FBA in the electrochemical determination of these compounds in water.",

keywords = "Cyclic voltammetry, Electrochemical determination, Ferroceneboronic acid, Phenolic compound, Pollutants in water, Sugar",

author = "Shigehiro Takahashi and Naoyuki Abiko and Nobuhiro Haraguchi and Hiroyuki Fujita and Eriko Seki and Tetsuya Ono and Kentaro Yoshida and Anzai, {Jun ichi}",

note = "Funding Information: The present work was supported in part by a Grant-in-Aid (Asia-Africa Program) from Tohoku University.",

year = "2011",

month = jun,

doi = "10.1016/S1001-0742(10)60509-8",

language = "English",

volume = "23",

pages = "1027--1032",

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T1 - Voltammetric response of ferroceneboronic acid to diol and phenolic compounds as possible pollutants

AU - Takahashi, Shigehiro

AU - Abiko, Naoyuki

AU - Haraguchi, Nobuhiro

AU - Fujita, Hiroyuki

AU - Seki, Eriko

AU - Ono, Tetsuya

AU - Yoshida, Kentaro

AU - Anzai, Jun ichi

N1 - Funding Information: The present work was supported in part by a Grant-in-Aid (Asia-Africa Program) from Tohoku University.

PY - 2011/6

Y1 - 2011/6

N2 - A voltammetric determination of possible organic pollutants such as diol and phenolic compounds in water was studied using ferroceneboronic acid (FBA) as a redox-active marker. A cyclic voltammogram of FBA exhibited a pair of oxidation and reduction peaks at 230 and 170 mV at pH 7.0, respectively, while another pair of redox peaks was observed in the presence of diol or phenolic compounds tested. The results were rationalized based on the formation of boronate esters of FBA with the added compounds. The changes in the redox peak currents were dependent on the concentration of the additives, suggesting a usefulness of FBA in the electrochemical determination of these compounds in water.

AB - A voltammetric determination of possible organic pollutants such as diol and phenolic compounds in water was studied using ferroceneboronic acid (FBA) as a redox-active marker. A cyclic voltammogram of FBA exhibited a pair of oxidation and reduction peaks at 230 and 170 mV at pH 7.0, respectively, while another pair of redox peaks was observed in the presence of diol or phenolic compounds tested. The results were rationalized based on the formation of boronate esters of FBA with the added compounds. The changes in the redox peak currents were dependent on the concentration of the additives, suggesting a usefulness of FBA in the electrochemical determination of these compounds in water.

KW - Cyclic voltammetry

KW - Electrochemical determination

KW - Ferroceneboronic acid

KW - Phenolic compound

KW - Pollutants in water

KW - Sugar

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U2 - 10.1016/S1001-0742(10)60509-8

DO - 10.1016/S1001-0742(10)60509-8

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AN - SCOPUS:79958804996

SN - 1001-0742

VL - 23

SP - 1027

EP - 1032

JO - Journal of Environmental Sciences (China)

JF - Journal of Environmental Sciences (China)

IS - 6

ER -

Voltammetric response of ferroceneboronic acid to diol and phenolic compounds as possible pollutants

Abstract

Keywords

ASJC Scopus subject areas

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