X-ray-induced phase transitions by selective excitation of heterometal ions in a cyanide-bridged Fe–Co molecular square

Yoshihiro Sekine; Masayuki Nihei; Reiji Kumai; Hironori Nakao; Youichi Murakami; Hiroki Oshio

doi:10.1039/c3cc48820a

X-ray-induced phase transitions by selective excitation of heterometal ions in a cyanide-bridged Fe–Co molecular square

Yoshihiro Sekine, Masayuki Nihei, Reiji Kumai, Hironori Nakao, Youichi Murakami, Hiroki Oshio

Materials Development Division

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

A cyanide-bridged tetranuclear Fe–Co complex showed electron-transfer-coupled spin transitions induced by X-ray irradiation. Single crystal X-ray diffraction measurements and X-ray absorption spectroscopy revealed that the X-ray-induced phase transition ratio was significantly altered by the selective excitation of the metal ions.

Original language	English
Pages (from-to)	4050-4052
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	31
DOIs	https://doi.org/10.1039/c3cc48820a
Publication status	Published - 2014 Mar 20

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "X-ray-induced phase transitions by selective excitation of heterometal ions in a cyanide-bridged Fe–Co molecular square",

abstract = "A cyanide-bridged tetranuclear Fe–Co complex showed electron-transfer-coupled spin transitions induced by X-ray irradiation. Single crystal X-ray diffraction measurements and X-ray absorption spectroscopy revealed that the X-ray-induced phase transition ratio was significantly altered by the selective excitation of the metal ions.",

author = "Yoshihiro Sekine and Masayuki Nihei and Reiji Kumai and Hironori Nakao and Youichi Murakami and Hiroki Oshio",

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T1 - X-ray-induced phase transitions by selective excitation of heterometal ions in a cyanide-bridged Fe–Co molecular square

AU - Sekine, Yoshihiro

AU - Nihei, Masayuki

AU - Kumai, Reiji

AU - Nakao, Hironori

AU - Murakami, Youichi

AU - Oshio, Hiroki

PY - 2014/3/20

Y1 - 2014/3/20

N2 - A cyanide-bridged tetranuclear Fe–Co complex showed electron-transfer-coupled spin transitions induced by X-ray irradiation. Single crystal X-ray diffraction measurements and X-ray absorption spectroscopy revealed that the X-ray-induced phase transition ratio was significantly altered by the selective excitation of the metal ions.

AB - A cyanide-bridged tetranuclear Fe–Co complex showed electron-transfer-coupled spin transitions induced by X-ray irradiation. Single crystal X-ray diffraction measurements and X-ray absorption spectroscopy revealed that the X-ray-induced phase transition ratio was significantly altered by the selective excitation of the metal ions.

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X-ray-induced phase transitions by selective excitation of heterometal ions in a cyanide-bridged Fe–Co molecular square

Abstract

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