TY - JOUR
T1 - X‐ray structure of 3‐diphenylmethylene‐2‐(2,4,6‐tri‐t‐butylphenyl)thiaphosphirane 2‐sulfide
T2 - The first thiaphosphirane with exo‐methylene
AU - Hirotsu, Ken
AU - Okamoto, Akihiro
AU - Toyota, Kozo
AU - Yoshifuji, Masaaki
PY - 1990/5
Y1 - 1990/5
N2 - The title compound was prepared by sulfurization of a 1‐phosphaallene and its x‐ray structure analysis showed the following notable features of the thiaphosphirane ring: P‐S = 2.101(2), P‐C = 1.770(5) and S‐C = 1.767(5) Å (remarkably short), and ∠SPC = 53.5(2), ∠PSC = 53.6(2) and ∠PCS = 72.9(2)°.
AB - The title compound was prepared by sulfurization of a 1‐phosphaallene and its x‐ray structure analysis showed the following notable features of the thiaphosphirane ring: P‐S = 2.101(2), P‐C = 1.770(5) and S‐C = 1.767(5) Å (remarkably short), and ∠SPC = 53.5(2), ∠PSC = 53.6(2) and ∠PCS = 72.9(2)°.
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U2 - 10.1002/hc.520010310
DO - 10.1002/hc.520010310
M3 - Article
AN - SCOPUS:84986405884
SN - 1042-7163
VL - 1
SP - 251
EP - 254
JO - Heteroatom Chemistry
JF - Heteroatom Chemistry
IS - 3
ER -