Abstract
After the observation of heavy-fermion characteristics in the charge-ordered phase of Yb4As3, it is surprising that Yb4(As0.71Sb0.29)3 shows heavy-fermion behavior, though the charge ordering is suppressed. To shed more light onto this enigma, we measured the optical reflectivity of Yb4(As0.71Sb0.29)3 at several temperatures down to 15 K in the photon energy range from 1 meV to 5.5 eV. The comparison of the optical functions of Yb4As3 and Yb4(As0.71Sb0.29)3 revealed decisive differences in the far-IR region. For the latter material, we found an hybridization gap of 3.3 meV, absent in Yb4As3. The effective mass of the conduction carriers takes the temperature-independent value of 2 me in Yb4As3, while m* shows a logarithmic temperature dependency and reaches 80 me at 15 K in Yb4(As0.71Sb0.29)3. This proves that two different mechanisms lead to a large y value in Yb4As3 and Yb4(As0.71Sb0.29)3.
Original language | English |
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Pages (from-to) | 345-346 |
Number of pages | 2 |
Journal | Journal of Magnetism and Magnetic Materials |
Volume | 177-181 |
Issue number | PART 1 |
DOIs | |
Publication status | Published - 1998 Jan |
Externally published | Yes |
Keywords
- Electronic phase transitions
- Heavy fermions
- Optical spectroscopy
- Rare-earth pnictides
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Condensed Matter Physics