TY - JOUR
T1 - A novel type of copper(II) dimers with tetradentate schiff bases
T2 - X-ray crystal structure and magnetic properties of bis-μ-[N,N′- ethylenebis(pyrrol-2-ylmethyleneaminato)]-dicopper(II)
AU - Kikuchi, Takemitsu
AU - Kabuto, Chizuko
AU - Yokoi, Hiroshi
AU - Iwaizumi, Masamoto
AU - Mori, Wasuke
PY - 1983/1/1
Y1 - 1983/1/1
N2 - The 1:1 complex of copper(II) with N,N′-ethylenebis(pyrrol-2- ylmethyleneamine) in benzene-inclusion crystals forms a novel copper(II) dimer in which each of the two interwined Schiff bases binds two copper atoms with a separation of 3.29 Å and with a strong antiferromagnetic interaction of J -61.2 cm-1 as shown by X-ray structural analysis and by magnetic susceptibility measurements.
AB - The 1:1 complex of copper(II) with N,N′-ethylenebis(pyrrol-2- ylmethyleneamine) in benzene-inclusion crystals forms a novel copper(II) dimer in which each of the two interwined Schiff bases binds two copper atoms with a separation of 3.29 Å and with a strong antiferromagnetic interaction of J -61.2 cm-1 as shown by X-ray structural analysis and by magnetic susceptibility measurements.
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U2 - 10.1039/C39830001306
DO - 10.1039/C39830001306
M3 - Article
AN - SCOPUS:37049109074
SN - 1359-7345
SP - 1306
EP - 1307
JO - Chemical Communications
JF - Chemical Communications
IS - 22
ER -