A stable 1,2-disilacyclohexene and its 14-electron palladium(0) complex

Takashi Abe, Takeaki Iwamoto, Mitsuo Kira

研究成果: ジャーナルへの寄稿学術論文査読

34 被引用数 (Scopus)

抄録

A novel stable cyclic disilene, 1,2-diphenyl-3,3,6,6- tetrakis(trimethylsilyl)-1,2-disilacyclohexene (1), was synthesized via the reaction of the corresponding 1,4-dilithiobutane with phenylchlorosilane. This new strategy would be applicable to the synthesis of stable cyclic disilenes having rather small residual substituents on unsaturated silicon atoms. A stable tricoordinate Y-shaped disilene palladium complex, 2, that was synthesized by the reaction of 1 with bis(tricyclohexylphosphine)palladium was found to have the strongest ?-complex character among known disilene palladium complexes.

本文言語英語
ページ(範囲)5008-5009
ページ数2
ジャーナルJournal of the American Chemical Society
132
14
DOI
出版ステータス出版済み - 2010 4月 14

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