A stable dialkylphosphinyl radical

研究成果: ジャーナルへの寄稿学術論文査読

80 被引用数 (Scopus)

抄録

Dialkylphosphinyl radical 1 was synthesized as thermally stable yellow crystals and found to be monomeric both in solution and in the solid state. EPR spectrum showed that the spin density of 1 is mainly localized on the 3p orbital of the dicoordinated phosphorus atom. A distinct absorption band due to the electronic transition from nonbonding electron pair orbital to singly occupied 3p orbital on the phosphorus atom of 1 was observed at 445 nm in solution. Phosphinyl radical 1 underwent facile reaction with carbon tetrachloride, hydrogen abstraction, and a unique reaction with a persistent radical, galvinoxyl, giving a cyclic phosphaalkene and a silylether.

本文言語英語
ページ(範囲)12968-12971
ページ数4
ジャーナルJournal of the American Chemical Society
133
33
DOI
出版ステータス出版済み - 2011 8月 24

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