Acceleration of environmental electrostatic potential using cholesky decomposition with adaptive metric (CDAM) for fragment molecular orbital (FMO) method

Yoshio Okiyama, Tatsuya Nakano, Chiduru Watanabe, Kaori Fukuzawa, Yuto Komeiji, Katsunori Segawa, Yuji Mochizuki

研究成果: Article査読

抄録

The calculation speed of the ab initio fragment molecular orbital (FMO) method can and must be increased by applying approximations to the environmental electrostatic potential (ESP) and the dimer electrostatic potential (dimer-es). These approximations were previously implemented by introducing the Cholesky decomposition with adaptive metric (CDAM) method to the FMO (Okiyama et al., Chem. Phys. Lett. 2010, 490, 84). In this study, a distributed memory algorithm of CDAM was introduced to reduce the necessary memory size. The improved version of CDAM was applied to the ESP approximation and was shown to give sufficiently precise energy values while halving the calculation time.

本文言語English
ページ(範囲)91-96
ページ数6
ジャーナルBulletin of the Chemical Society of Japan
94
1
DOI
出版ステータスPublished - 2021
外部発表はい

ASJC Scopus subject areas

  • 化学 (全般)

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