Acylation of Alkenes with the Aid of AlCl3 and 2,6-Dibromopyridine

Shinya Tanaka; Tsukasa Kunisawa; Yuji Yoshii; Tetsutaro Hattori

doi:10.1021/acs.orglett.9b02688

Acylation of Alkenes with the Aid of AlCl₃ and 2,6-Dibromopyridine

Shinya Tanaka, Tsukasa Kunisawa, Yuji Yoshii, Tetsutaro Hattori

工学研究科・バイオ工学専攻

研究成果: Article › 査読

6 被引用数 (Scopus)

抄録

Friedel-Crafts-type acylation of alkenes with acyl chlorides has been successfully conducted with a wide substrate scope by the combined use of AlCl₃ and 2,6-dibromopyridine. Trisubstituted alkenes afford allylketones or vinylketones depending on the presence or absence of hydrogen atom(s) at the β-position to the acylation site, while monosubstituted alkenes exclusively afford vinylketones.

本文言語	English
ページ（範囲）	8509-8513
ページ数	5
ジャーナル	Organic letters
巻	21
号	21
DOI	https://doi.org/10.1021/acs.orglett.9b02688
出版ステータス	Published - 2019 11月 1

ASJC Scopus subject areas

生化学
物理化学および理論化学
有機化学

文献へのアクセス

10.1021/acs.orglett.9b02688

他のファイルとリンク

引用スタイル

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author = "Shinya Tanaka and Tsukasa Kunisawa and Yuji Yoshii and Tetsutaro Hattori",

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