Ca0.8Y2.4Sn0.8O6, a quaternary oxide with mixed occupations of Ca/Y and Y/Sn

Yusuke Kaminaga; Hisanori Yamane; Takahiro Yamada

doi:10.1107/S0108270106017586

Ca_0.8Y_2.4Sn_0.8O₆, a quaternary oxide with mixed occupations of Ca/Y and Y/Sn

Yusuke Kaminaga, Hisanori Yamane, Takahiro Yamada

研究成果: Article › 査読

3 被引用数 (Scopus)

抄録

A new quaternary oxide, calcium yttrium stannate, Ca_0.8Y _2.4Sn_0.8O₆, is isostructural with Mg ₃TeO₆ (trigonal, R3̄). The empirical formula can be expressed as (Ca_0.2667Y_0.7333)₆(Y _0.4Sn_0.6)SnO₁₂. The Ca/Y site has a distorted coordination octahedron of O atoms, with Ca/Y-O distances ranging from 2.227 (3) to 2.350 (3) Å, while the octahedra of O atoms that coordinate to the Sn and Y/Sn sites are nearly regular, with an Sn-O distance of 2.066 (2) Å and a Y/Sn-O distance of 2.147 (3) Å.

本文言語	English
ページ（範囲）	i57-i58
ジャーナル	Acta Crystallographica Section C: Crystal Structure Communications
巻	62
号	7
DOI	https://doi.org/10.1107/S0108270106017586
出版ステータス	Published - 2006 7月 1

ASJC Scopus subject areas

生化学、遺伝学、分子生物学（全般）

文献へのアクセス

10.1107/S0108270106017586

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引用スタイル

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title = "Ca0.8Y2.4Sn0.8O6, a quaternary oxide with mixed occupations of Ca/Y and Y/Sn",

abstract = "A new quaternary oxide, calcium yttrium stannate, Ca0.8Y 2.4Sn0.8O6, is isostructural with Mg 3TeO6 (trigonal, R{\=3}). The empirical formula can be expressed as (Ca0.2667Y0.7333)6(Y 0.4Sn0.6)SnO12. The Ca/Y site has a distorted coordination octahedron of O atoms, with Ca/Y-O distances ranging from 2.227 (3) to 2.350 (3) {\AA}, while the octahedra of O atoms that coordinate to the Sn and Y/Sn sites are nearly regular, with an Sn-O distance of 2.066 (2) {\AA} and a Y/Sn-O distance of 2.147 (3) {\AA}.",

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N2 - A new quaternary oxide, calcium yttrium stannate, Ca0.8Y 2.4Sn0.8O6, is isostructural with Mg 3TeO6 (trigonal, R3̄). The empirical formula can be expressed as (Ca0.2667Y0.7333)6(Y 0.4Sn0.6)SnO12. The Ca/Y site has a distorted coordination octahedron of O atoms, with Ca/Y-O distances ranging from 2.227 (3) to 2.350 (3) Å, while the octahedra of O atoms that coordinate to the Sn and Y/Sn sites are nearly regular, with an Sn-O distance of 2.066 (2) Å and a Y/Sn-O distance of 2.147 (3) Å.

AB - A new quaternary oxide, calcium yttrium stannate, Ca0.8Y 2.4Sn0.8O6, is isostructural with Mg 3TeO6 (trigonal, R3̄). The empirical formula can be expressed as (Ca0.2667Y0.7333)6(Y 0.4Sn0.6)SnO12. The Ca/Y site has a distorted coordination octahedron of O atoms, with Ca/Y-O distances ranging from 2.227 (3) to 2.350 (3) Å, while the octahedra of O atoms that coordinate to the Sn and Y/Sn sites are nearly regular, with an Sn-O distance of 2.066 (2) Å and a Y/Sn-O distance of 2.147 (3) Å.

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