Design of flexible lewis acidic sites in porous coordination polymers by using the viologen moiety

Masakazu Higuchi, Kohei Nakamura, Satoshi Horike, Yuh Hijikata, Nobuhiro Yanai, Tomohiro Fukushima, Jungeun Kim, Kenichi Kato, Masaki Takata, Daisuke Watanabe, Shinji Oshima, Susumu Kitagawa

研究成果: Article査読

71 被引用数 (Scopus)

抄録

Charged up: A novel porous coordination polymer with a charged organic surface (COS) comprising a zwitterionic organic linker, viologen, has been synthesized. The COS shows strong Lewis acidity accompanied with flexibility, and the isosteric heat of H2 adsorption is 9.5 kJ mol-1, which is comparable to that of open metal sites (OMSs).

本文言語English
ページ(範囲)8369-8372
ページ数4
ジャーナルAngewandte Chemie - International Edition
51
33
DOI
出版ステータスPublished - 2012 8月 13
外部発表はい

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)

フィンガープリント

「Design of flexible lewis acidic sites in porous coordination polymers by using the viologen moiety」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル