抄録
A large class of new layered semiconductors - lead iodide compounds - is of great interest because of possible optoelectronic applications due to pronounced excitonic effects. These compounds may be regarded as naturally grown semiconductor/insulator superlattices, with perovskite lead iodide (semiconductor) layers sandwiched by alkylammonium (insulator) layers. Exciton binding energies and oscillator strength in these structures are enhanced due to the so-called `dielectric confinement' caused by large difference between dielectric constants of adjoining layers. The binding energies, wave functions, & diamagnetic coefficient of excitons in these naturally grown superlattices are calculated with allowance for the image potential and the superlattice structure of the compounds. The localization of excitons in lead iodide layers causes also a strong dependence of a polariton spike in reflection spectra on the polarization of electromagnetic wave. The results obtained are in agreement with the experimental data.
本文言語 | English |
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ホスト出版物のタイトル | Electrical, Optical, and Magnetic Properties of Organic Solid State Materials |
編集者 | Anthony F. Garito, Alex K-Y. Jen, Charles Y-C. Lee, Larry R. Dalton |
出版社 | Publ by Materials Research Society |
ページ | 775-780 |
ページ数 | 6 |
巻 | 328 |
ISBN(印刷版) | 1558992278 |
出版ステータス | Published - 1994 1月 1 |
外部発表 | はい |
イベント | Proceedings of the MRS 1993 Fall Meeting - Boston, MA, USA 継続期間: 1993 11月 29 → 1993 12月 3 |
Other
Other | Proceedings of the MRS 1993 Fall Meeting |
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City | Boston, MA, USA |
Period | 93/11/29 → 93/12/3 |
ASJC Scopus subject areas
- 電子材料、光学材料、および磁性材料