Direct observation of photochromic dynamics in the crystalline state of an organorhodium dithionite complex

Hidetaka Nakai, Motohiro Mizuno, Takanori Nishioka, Nobuaki Koga, Kimie Shiomi, Yousuke Miyano, Masahiro Irie, Brian K. Breedlove, Isamu Kinoshita, Yoshihito Hayashi, Yoshiki Ozawa, Takae Yonezawa, Koshiro Toriumi, Kiyoshi Isobe

研究成果: Article査読

33 被引用数 (Scopus)

抄録

(Chemical Equation Presented) Fully reversible crystal photochromism between the μ-O2SSO2 (1) and μ-O2SOSO (2) forms of a dinuclear rhodium complex has been observed. The photochromic reaction, including stereoselective oxygen-atom transfer and stereospecific transformation of photochemically generated μ-O2SOSO isomers into the most stable isomer, was directly followed by conventional single-crystal X-ray diffraction.

本文言語English
ページ(範囲)6473-6476
ページ数4
ジャーナルAngewandte Chemie - International Edition
45
39
DOI
出版ステータスPublished - 2006 10月 6
外部発表はい

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)

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