TY - JOUR
T1 - Enantioselective [2,3]] sigmatropic rearrangement of α- propargyloxyacetic acids mediated by BuLi-(-)-sparteine complex
AU - Manabe, Shino
N1 - Copyright:
Copyright 2018 Elsevier B.V., All rights reserved.
PY - 1998/2
Y1 - 1998/2
N2 - The [2,3] sigmatropic rearrangement of α-propargyloxyacetic acids was achieved by the use of BaLi-(-)-sparteine complex in toluene. BuLi-chiral ligand complexes are stronger bases than lithium amides, so they are expected to be good mediators of this reaction.
AB - The [2,3] sigmatropic rearrangement of α-propargyloxyacetic acids was achieved by the use of BaLi-(-)-sparteine complex in toluene. BuLi-chiral ligand complexes are stronger bases than lithium amides, so they are expected to be good mediators of this reaction.
KW - BuLi-(-)-sparteine complex
KW - Chiral allenylalcohol
KW - Enantioselective [2,3]-sigmatropic rearrangement
KW - α-propargyloxy acetic acid
UR - http://www.scopus.com/inward/record.url?scp=0031916818&partnerID=8YFLogxK
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U2 - 10.1248/cpb.46.335
DO - 10.1248/cpb.46.335
M3 - Article
AN - SCOPUS:0031916818
SN - 0009-2363
VL - 46
SP - 335
EP - 336
JO - Chemical and Pharmaceutical Bulletin
JF - Chemical and Pharmaceutical Bulletin
IS - 2
ER -