Generation of Aromatic (Dehydro)benzoannulene Dications Stabilized by Platinum Catecholate Complexes

Kazukuni Tahara, Hiroyoshi Kozuma, Varadhachari Venkatesh, Eri Ryomura, Hirokazu Miyoshi, Keigo Nakamachi, Ryohei Kishi, Hideaki Takahashi, Masayoshi Nakano, Yoshito Tobe

研究成果: ジャーナルへの寄稿学術論文査読

7 被引用数 (Scopus)

抄録

A dehydrobenzo[12]annulene attached by three platinum catecholate units is oxidized chemically or electrochemically to generate mono-, di-, and trications. Similarly, a platinum catecholate complex with a dibenzo[8]annulene framework also generates mono- and dications upon oxidation. On the basis of theoretical and spectroscopic studies with respect to energetic, structural, and magnetic criteria, these dications are deduced to be aromatic, thus demonstrating a new method for stabilizing aromatic dications.

本文言語英語
ページ(範囲)1052-1056
ページ数5
ジャーナルChemPlusChem
82
7
DOI
出版ステータス出版済み - 2017 8月 1

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