High-pressure synthesis of a new calcium thioborate, CaB
                        2
                        S
                        4

Takeshi Sasaki; Hirotsugu Takizawa; Takashi Takeda; Tadashi Endo

doi:10.1016/S0025-5408(02)01005-X

High-pressure synthesis of a new calcium thioborate, CaB ₂ S ₄

Takeshi Sasaki, Hirotsugu Takizawa, Takashi Takeda, Tadashi Endo

執行部

研究成果: Article › 査読

11 被引用数 (Scopus)

抄録

A new calcium thioborate, CaB ₂ S ₄ , was synthesized at high-pressure/temperature condition of 6.2GPa and 800-1100°C. The crystal structure was refined by the Rietveld method using powder X-ray diffraction data. The compound crystallizes into a cubic unit cell (a=11.210Å, space group: Pa3), isostructural with a high-pressure polymorph of calcium borate, CaB ₂ O ₄ -IV. The unit cell consists of three-dimensional linkage of BS ₄ -tetrahedra, and calcium atoms have coordination number of 12.

本文言語	English
ページ（範囲）	33-39
ページ数	7
ジャーナル	Materials Research Bulletin
巻	38
号	1
DOI	https://doi.org/10.1016/S0025-5408(02)01005-X
出版ステータス	Published - 2003 1月 1

ASJC Scopus subject areas

材料科学（全般）
凝縮系物理学
材料力学
機械工学

文献へのアクセス

10.1016/S0025-5408(02)01005-X

他のファイルとリンク

引用スタイル

@article{34a5809535f04ad486512b1d347b4c47,

title = " High-pressure synthesis of a new calcium thioborate, CaB 2 S 4 ",

abstract = " A new calcium thioborate, CaB 2 S 4 , was synthesized at high-pressure/temperature condition of 6.2GPa and 800-1100°C. The crystal structure was refined by the Rietveld method using powder X-ray diffraction data. The compound crystallizes into a cubic unit cell (a=11.210{\AA}, space group: Pa3), isostructural with a high-pressure polymorph of calcium borate, CaB 2 O 4 -IV. The unit cell consists of three-dimensional linkage of BS 4 -tetrahedra, and calcium atoms have coordination number of 12.",

keywords = "Chalcogenides, Chemical synthesis, Crystal structure, High pressure, Inorganic compounds, X-ray diffraction",

author = "Takeshi Sasaki and Hirotsugu Takizawa and Takashi Takeda and Tadashi Endo",

year = "2003",

month = jan,

day = "1",

doi = "10.1016/S0025-5408(02)01005-X",

language = "English",

volume = "38",

pages = "33--39",

journal = "Materials Research Bulletin",

issn = "0025-5408",

publisher = "Elsevier Limited",

number = "1",

}

TY - JOUR

T1 - High-pressure synthesis of a new calcium thioborate, CaB 2 S 4

AU - Sasaki, Takeshi

AU - Takizawa, Hirotsugu

AU - Takeda, Takashi

AU - Endo, Tadashi

PY - 2003/1/1

Y1 - 2003/1/1

N2 - A new calcium thioborate, CaB 2 S 4 , was synthesized at high-pressure/temperature condition of 6.2GPa and 800-1100°C. The crystal structure was refined by the Rietveld method using powder X-ray diffraction data. The compound crystallizes into a cubic unit cell (a=11.210Å, space group: Pa3), isostructural with a high-pressure polymorph of calcium borate, CaB 2 O 4 -IV. The unit cell consists of three-dimensional linkage of BS 4 -tetrahedra, and calcium atoms have coordination number of 12.

AB - A new calcium thioborate, CaB 2 S 4 , was synthesized at high-pressure/temperature condition of 6.2GPa and 800-1100°C. The crystal structure was refined by the Rietveld method using powder X-ray diffraction data. The compound crystallizes into a cubic unit cell (a=11.210Å, space group: Pa3), isostructural with a high-pressure polymorph of calcium borate, CaB 2 O 4 -IV. The unit cell consists of three-dimensional linkage of BS 4 -tetrahedra, and calcium atoms have coordination number of 12.

KW - Chalcogenides

KW - Chemical synthesis

KW - Crystal structure

KW - High pressure

KW - Inorganic compounds

KW - X-ray diffraction

UR - http://www.scopus.com/inward/record.url?scp=0037216698&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0037216698&partnerID=8YFLogxK

U2 - 10.1016/S0025-5408(02)01005-X

DO - 10.1016/S0025-5408(02)01005-X

M3 - Article

AN - SCOPUS:0037216698

SN - 0025-5408

VL - 38

SP - 33

EP - 39

JO - Materials Research Bulletin

JF - Materials Research Bulletin

IS - 1

ER -

High-pressure synthesis of a new calcium thioborate, CaB 2 S 4

抄録

ASJC Scopus subject areas

文献へのアクセス

他のファイルとリンク

フィンガープリント

引用スタイル

High-pressure synthesis of a new calcium thioborate, CaB ₂ S ₄