Hydrogen release reactions of Al-based complex hydrides enhanced by vibrational dynamics and valences of metal cations

T. Sato, A. J. Ramirez-Cuesta, L. Daemen, Y. Q. Cheng, K. Tomiyasu, Shigeyuki Takagi, S. Orimo

研究成果: ジャーナルへの寄稿学術論文査読

10 被引用数 (Scopus)

抄録

Hydrogen release from Al-based complex hydrides composed of metal cation(s) and [AlH4]- was investigated using inelastic neutron scattering viewed from vibrational dynamics. The hydrogen release followed the softening of translational and [AlH4]- librational modes, which was enhanced by vibrational dynamics and the valence(s) of the metal cation(s).

本文言語英語
ページ(範囲)11807-11810
ページ数4
ジャーナルChemical Communications
52
79
DOI
出版ステータス出版済み - 2016

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